907111
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide
powder or crystals
동의어(들):
(bpp)NiBr2
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크기 선택
보기 변경
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C11H9Br2N5Ni
CAS 번호:
Molecular Weight:
429.72
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
제품 이름
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide,
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
SMILES string
[Ni+].[Br-].Br.[n]3(nccc3)c1nc(ccc1)[n]2nccc2
InChI
1S/C11H9N5.2BrH.Ni/c1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;;;/h1-9H;2*1H;/q;;;+1/p-1
InChI key
ZVPBBPDZLUQKSN-UHFFFAOYSA-M
Application
Precatalyst for alkyl-alkyl cross-coupling; reductive cross-coupling of styrenyl aziridines, dialkyl ether formation, reductive amination.
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
관련 콘텐츠
Doyle group focuses on nucleophilic fluorination using PyFluor and nickel catalysis with modular, air-stable nickel precatalyst.
Christoph Heinz et al.
Journal of the American Chemical Society, 140(6), 2292-2300 (2018-01-18)
This report describes a three-component, Ni-catalyzed reductive coupling that enables the convergent synthesis of tertiary benzhydryl amines, which are challenging to access by traditional reductive amination methodologies. The reaction makes use of iminium ions generated in situ from the condensation
국제 무역 품목 번호
| SKU | GTIN |
|---|---|
| 907111-250MG | 04022536041520 |