[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

Name: [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
Brand: ALDRICH

powder

동의어(들):

(1,3-dppp)NiCl₂, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl₂

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:

[(C₆H₅)₂P(CH₂)₃P(C₆H₅)₂]NiCl₂

CAS 번호:

15629-92-2

Molecular Weight:

542.04

UNSPSC Code:

12161600

PubChem Substance ID:

24860309

NACRES:

NA.22

MDL number:

MFCD00015318

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속성

제품 이름

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II),

form

powder

Quality Level

100

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

mp

213 °C (dec.) (lit.)

SMILES string

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key

ZBQUMMFUJLOTQC-UHFFFAOYSA-L

설명

Application

Catalyst for:

Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.