902993
(BPhen)Ni(OAc)2.xH2O
≥95%, powder or crystals
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C28H22N2NiO4
CAS 번호:
Molecular Weight:
509.18
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
제품 이름
(BPhen)Ni(OAc)2.xH2O,
assay
≥95%
form
powder or crystals
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
>300 °C
SMILES string
O=C(O[Ni]OC(C)=O)C.C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5
InChI
1S/C24H16N2.2C2H4O2.Ni/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*1-2(3)4;/h1-16H;2*1H3,(H,3,4);/q;;;+2/p-2
InChI key
DONATKZVTHVGHJ-UHFFFAOYSA-L
Application
Catalyst for cross couplings via C-N bond activation
Disclaimer
Store under N2 atmosphere
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
문서
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Corey H Basch et al.
Journal of the American Chemical Society, 139(15), 5313-5316 (2017-04-01)
We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation