919780
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads
solid
동의어(들):
Pd(dppf)Cl2
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크기 선택
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(C17H14P)2Fe . PdCl2
CAS 번호:
MDL number:
UNSPSC Code:
12352103
NACRES:
NA.22
제품 이름
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads,
Quality Level
product line
ChemBeads
form
solid
composition
~ 4 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
[Pd+2].[Fe+2].P(c6c[c-H]cc6)(c5ccccc5)c4ccccc4.P(c3c[c-H]cc3)(c2ccccc2)c1ccccc1.[Cl-].[Cl-]
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2
InChI key
NXQGGXCHGDYOHB-UHFFFAOYSA-L
Application
Catalyst for C-C and C-N coupling reaction.
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (697230) & (931217)
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (697230) & (931217)
Other Notes
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
signalword
Danger
hcodes
Hazard Classifications
Carc. 1B Inhalation
저장 등급
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling reaction of a secondary alkyl grignard reagent with organic halides
Hayashi T, et al.
Tetrahedron Letters, 20(21), 1871-1874 (1979)
Star−Shaped Oligothiophenes for Solution−Processible Organic Field-Effect Transistors
Ponomarenko S A, et al.
Advances in Functional Materials, 13(8), 591-596 (2003)
Sho Fujii et al.
Physical chemistry chemical physics : PCCP, 19(42), 28943-28949 (2017-10-24)
A novel sensor, 4-[2-(9-anthryl)ethynyl]-1,10-phenanthroline (1), exhibits highly intense fluorescent in the wavelength region of 440-600 nm (maximum wavelength (λf) = 470 nm) with the quantum yield (Φf) and lifetime (τf) being 0.90 and 4.2 ns, respectively, in CH3CN at 298
국제 무역 품목 번호
| SKU | GTIN |
|---|---|
| 919780-250MG | 04065265473910 |
| 919780-1G | 04065265473903 |