주요 문서

모든 문서 보기

697230

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Name: [1,1&#8242;-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Brand: ALDRICH

powder

동의어(들):

Pd(dppf)Cl₂

조직 및 계약 가격을 보려면 로그인를 클릭합니다.

크기 선택

보기 변경

제품정보 (DICE 배송 시 비용 별도)

Linear Formula:

(C₁₇H₁₄P)₂Fe · PdCl₂

CAS 번호:

72287-26-4

Molecular Weight:

731.70

NACRES:

NA.22

PubChem Substance ID:

329761901

UNSPSC Code:

12161600

EC Number:

460-040-3

MDL number:

MFCD00015757

기술 서비스

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도움 문의

속성

제품 이름

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II),

form

powder

Quality Level

200

reaction suitability

core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

266-283 °C (lit.)

SMILES string

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

JCWIWBWXCVGEAN-UHFFFAOYSA-L

설명

Application

Pd(dppf)Cl₂ may be used as an effective palladium catalyst in the following reactions:

Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [¹¹C]methyl iodide to form functionalized [¹¹C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

For small scale and high throughput uses, product is also available as ChemBeads (919780)

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for C-C and C-N coupling reaction.

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저장 등급

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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시험 성적서(COA)

Lot/Batch Number

92496LJ

01407BJ

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문서 라이브러리 방문

문서

Syntheses of Functionalized Alkenes, Arenes, and Cycloalkenes via a Hydroboration-Coupling Sequence

Tandem hydroboration Suzuki Coupling both intermolecular and intramolecular gave diverse alkyl substituted products dppf

Palladium-catalysed cyclisation of N-alkynyl aminomalonates.

Wilfried Hess et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 16(41), 12303-12306 (2010-09-15)

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

Shunsuke Chiba et al.

Journal of the American Chemical Society, 131(36), 12886-12887 (2009-08-25)

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

Electrophilic activation of benzaldehydes through ortho palladation: one-pot synthesis of 3-methylene-indan-1-ols through a domino allylstannylation/Heck reaction under neutral conditions.

Ján Cvengros et al.

Angewandte Chemie (International ed. in English), 48(33), 6148-6151 (2009-07-11)

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국제 무역 품목 번호

SKU	GTIN
697230-5G	04061832786308
697230-1G	04061832786131
697230-250G	04061833550946
697230-25G	04065271068131

주요 문서

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

powder

크기 선택

제품정보 (DICE 배송 시 비용 별도)

제품 이름

form

Quality Level

reaction suitability

mp

SMILES string

InChI

InChI key

Application

Still not finding the right product?

안전성 정보

저장 등급

wgk

flash_point_f

flash_point_c

문서

시험 성적서(COA)

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