주요 문서

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296309

1,4-Dioxane

Name: 1,4-Dioxane
Brand: SIAL

anhydrous, 99.8%, contains <=25 ppm BHT as stabilizer

동의어(들):

Diethylene oxide, Dioxane

조직 및 계약 가격을 보려면 로그인를 클릭합니다.

크기 선택

보기 변경

제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):

C₄H₈O₂

CAS 번호:

123-91-1

Molecular Weight:

88.11

UNSPSC Code:

12352005

NACRES:

NA.21

PubChem Substance ID:

57648388

EC Number:

204-661-8

Beilstein/REAXYS Number:

102551

MDL number:

MFCD00006571

Assay:

99.8%

Grade:

anhydrous

Bp:

100-102 °C (lit.)

Vapor pressure:

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

기술 서비스

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도움 문의

속성

grade

anhydrous

Quality Level

200

vapor density

3 (vs air)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

99.8%

form

liquid

autoignition temp.

356 °F

expl. lim.

22 %

impurities

<0.003% water, <0.005% water (100 mL pkg)

evapn. residue

≤0.005%

refractive index

n20/D 1.422 (lit.)

pH

6.0-8 (20 °C, 500 g/L)

bp

100-102 °C (lit.)

mp

10-12 °C (lit.)

density

1.034 g/mL at 25 °C (lit.)

SMILES string

C1COCCO1

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

InChI key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

설명

Application

1,4-Dioxane may undergo nickel-catalyzed oxidative arylation with arylboronic acids to form α-arylated ethers.
It may be used as a solvent to synthesize:

(Chloromethyl)dimethylphenylsilane from chloro(chloromethyl)dimethylsilane via zinc-catalyzed substitution reaction with phenylmagnesium bromide.
N-(2,2,2-trifluoro-1-hydroxyethyl)-acetamide from 2,2,2-trifluoro-1-methoxyethanol and acetamide.

Packaging

View returnable container options.

Other Notes

The article number 296309-4X2L will be discontinued. Please order the single bottle 296309-2L which is physically identical with the same exact specifications.

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pictograms

GHS02,GHS08,GHS07

signalword

Danger

hcodes

H225,H319,H335,H350

pcodes

P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019,EUH066

저장 등급

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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문서

Solvent Miscibility Table

Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.

Scale-Up Guide: Buchwald-Hartwig Amination

Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.

용매 혼용성 표

물질이 용해되어 균일한 용액을 형성하면 서로 섞일 수 있다고 합니다. 일반적인 실험용 용매에 대한 혼용성 표를 북마크하거나 다운로드하세요.

모든 기사 보기

Synthesis of tetraorganosilanes: (chloromethyl)dimethylphenylsilane

Murakami K, et al.

Organic Syntheses, 87, 178-178 (2010)

A xanthate-transfer approach to ?-trifluoromethylamines

Gagosz F and Zard FS

Organic Syntheses, 84, 32-32 (2007)

Solubility of anthracene in binary alcohol+ 1,4-dioxane solvent mixtures.

Powell JR, et al.

Journal of Chemical and Engineering Data, 40(5), 1124-1126 (1995)

모든 관련된 서류 보기

국제 무역 품목 번호

SKU	GTIN
296309-100ML	04061837532733
296309-200L	04061838161437
296309-200L-KL	04061838151940
296309-6X1L	04061826649930
296309-12X100ML	04061826649459
296309-18L	04061838161420
296309-1L	04061837532757
296309-250ML	04061837536885
296309-2L	04061837532764