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Merck

207802

Potassium dichromate

ACS reagent, ≥99.0%

동의어(들):

Potassium bichromate

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
K2Cr2O7
CAS 번호:
Molecular Weight:
294.18
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-906-6
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
crystals
Solubility:
water: soluble (ca.29.4 g/l at 20 °C (68 °F))
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grade

ACS reagent

Quality Level

assay

≥99.0%

form

crystals

reaction suitability

reagent type: oxidant

impurities

≤0.005% insolubles

loss

≤0.05% loss on drying

pH

3.5-5.0 (25 °C, 29.4 g/L)

mp

398 °C (lit.)

solubility

water: soluble (ca.29.4 g/l at 20 °C (68 °F))

anion traces

chloride (Cl-): ≤0.001%, sulfate (SO42-): ≤0.005%

cation traces

Ca: ≤0.003%, Na: ≤0.001%, Na: ≤0.02%, heavy metals (as Pb): ≤5 ppm

SMILES string

[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

InChI

1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1

InChI key

KMUONIBRACKNSN-UHFFFAOYSA-N

General description

Potassium dichromate is a red-orange colored solid. Its crystals belong to the triclinic crystal system. On heating above 600°C, it decomposes to give oxygen, potassium chromate and chromium(III) oxide. It acts as a strong oxidizing agent in acidic media. It can be synthesized by the fusion of chromium(III) oxide with potassium carbonate and nitrate or oxygen.

Application

Potassium dichromate may be used in the preparation of hybride polymer-clay nanocomposite supported dichromate reagents. It may also be used as an oxidant for the selective oxidation of primary and secondary alcohol to corresponding aldehydes and ketones, respectively.


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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Cardio-vascular system, Respiratory system

저장 등급

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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문서 라이브러리 방문



Selective solvent-free oxidation of alcohols with potassium dichromate
Lou J-D and Xu Z-N
Tetrahedron Letters, 43(49), 8843-8844 (2002)
Nicholas James Strausfeld et al.
eLife, 9 (2020-03-04)
Descriptions of crustacean brains have focused mainly on three highly derived lineages of malacostracans: the reptantian infraorders represented by spiny lobsters, lobsters, and crayfish. Those descriptions advocate the view that dome- or cap-like neuropils, referred to as 'hemiellipsoid bodies,' are
Marcel E Sayre et al.
The Journal of comparative neurology, 527(14), 2371-2387 (2019-03-13)
Paired centers in the forebrain of insects, called the mushroom bodies, have become the most investigated brain region of any invertebrate due to novel genetic strategies that relate unique morphological attributes of these centers to their functional roles in learning



국제 무역 품목 번호

SKUGTIN
207802-500G04061837768361
207802-100G04061837768354