1,8-Diazabicyclo[5.4.0]undec-7-ene

Name: 1,8-Diazabicyclo[5.4.0]undec-7-ene
Brand: SIAL

puriss., ≥99.0% (GC)

동의어(들):

2,3,4,6,7,8,9,10-Octahydropyrimidol[1,2-a]azepine, DBU

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크기 선택

제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):

C₉H₁₆N₂

Molecular Weight:

152.24

Beilstein:

508906

EC Number:

229-713-7

MDL number:

MFCD00006930

UNSPSC 코드:

12352005

PubChem Substance ID:

329754558

NACRES:

NA.22

주요 문서

모든 문서 보기

기술 서비스

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도움 문의

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도움 문의

vapor pressure

7.1 hPa ( 37.7 °C)

Quality Level

200

grade

puriss.

분석

≥99.0% (GC)

양식

liquid

refractive index

n20/D 1.523

pH

(12,8 at 10 g/l at 20 °C)

bp

115 °C/11 mmHg (lit.)

mp

-70 °C

density

1.019 g/mL at 20 °C (lit.)

SMILES string

C1CCN2CCCN=C2CC1

InChI

1S/C9H16N2/c1-2-5-9-10-6-4-8-11(9)7-3-1/h1-8H2

InChI key

GQHTUMJGOHRCHB-UHFFFAOYSA-N

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일반 설명

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애플리케이션

1,8-Diazabicyclo[5.4.0]undec-7-ene can be used:

To mediate the aza-Michael addition of nitrogen nucleophiles to α,β-unsaturated carbonyl compounds.
As a nucleophilic catalyst for the esterification of carboxylic acid with dimethyl carbonate.
As a bidentate ligand in copper (I) bromide mediated atom transfer radical polymerization of methyl methacrylate.
As an efficient catalyst for the transesterification of dimethyl carbonate with glycerol.

Amidine base used for dehydrohalogenation reactions to olefinscitation; Further important applications are e.g.: esterification of carboxylic acids with alkyl halidescitationcitation; Alkylation and acylation of active methylene compoundscitation

기타 정보

Amidine base used for dehydrohalogenation reactions to olefins; Further important applications are e.g.: esterification of carboxylic acids with alkyl halides; Alkylation and acylation of active methylene compounds.