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271004

Acetonitrile

Name: Acetonitrile
Brand: SIAL

99.8%, anhydrous, suitable for solid phase extraction (SPE)

동의어(들):

Methyl cyanide, Anhydrous ACN, Dry MeCN

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:

CH₃CN

CAS 번호:

75-05-8

Molecular Weight:

41.05

NACRES:

NA.21

PubChem Substance ID:

57648217

eCl@ss:

39031501

UNSPSC Code:

12191502

EC Number:

200-835-2

MDL number:

MFCD00001878

Beilstein/REAXYS Number:

741857

Assay:

99.8%

Grade:

anhydrous

Technique(s):

solid phase extraction (SPE): suitable

Bp:

81-82 °C (lit.)

Vapor pressure:

72.8 mmHg ( 20 °C)

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도움 문의

속성

제품 이름

Acetonitrile, anhydrous, 99.8%

grade

anhydrous

Quality Level

200

vapor density

1.41 (vs air)

vapor pressure

72.8 mmHg ( 20 °C)

assay

99.8%

form

liquid

autoignition temp.

973 °F

expl. lim.

16 %

technique(s)

solid phase extraction (SPE): suitable

impurities

<0.001% water, <0.005% water (100 mL pkg)

evapn. residue

<0.0005%

color

colorless

refractive index

n20/D 1.344 (lit.)

bp

81-82 °C (lit.)

mp

−45 °C (lit.)

solubility

water: soluble (completely)

density

0.786 g/mL at 25 °C (lit.)

format

neat

SMILES string

CC#N

InChI

1S/C2H3N/c1-2-3/h1H3

InChI key

WEVYAHXRMPXWCK-UHFFFAOYSA-N

설명

General description

Acetonitrile, an aliphatic nitrile, is widely used as an organic solvent and intermediate in organic syntheses. It is transparent to UV-visible light, which makes it highly applicable in spectrophotometric and fluorimetric techniques. MeCN is utilized as a mobile phase component in many chromatographic techniques, due to its low viscosity, high elution strength and miscibility in water. It also plays a major role as an extractant medium in liquid-liquid extraction, solid-phase extraction or microextraction.

Application

Acetonitrile may be used as a solvent to prepare:

1,2-Azidoalcohols and 1,2-azidoamines via cerium(III) chloride assisted ring opening of epoxides and aziridines by sodium azide.
Cyano-bearing indolinones by oxidative arylalkylation of olefins in the presence of palladium catalyst.

It may also be used as a reactant to synthesize:

Bis (diphenylphosphino) acetonitrile by reacting with n-butyllithium and then with chlorodiphenylphosphine.
β-Acetamido ketones via coupling reaction with ketones or ketoesters and aldehydes in the presence of cobalt(II) chloride.

Packaging

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pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H302 + H312 + H332,H319

pcodes

P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

저장 등급

3 - Flammable liquids

flash_point_f

35.6 °F - closed cup

flash_point_c

2.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Solvent Miscibility Table

Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.

용매 혼용성 표

물질이 용해되어 균일한 용액을 형성하면 서로 섞일 수 있다고 합니다. 일반적인 실험용 용매에 대한 혼용성 표를 북마크하거나 다운로드하세요.

Bis (diphenylphosphino) acetonitrile: Synthesis, ligand properties and application in catalytic carbon?carbon coupling

Braun L, et al.

Dalton Transactions, 14, 1409-1415 (2007)

Cobalt-catalysed three-component coupling involving ketones or ketoesters, aldehydes and acetonitrile: a novel one-pot synthesis of ?-acetamido ketones

Madhavaa Reddy M.

Journal of the Chemical Society. Chemical Communications, 6, 713-714 (1994)

Eagleson M.

Concise Encyclopedia Chemistry, 56-56 (1994)

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국제 무역 품목 번호

SKU	GTIN
271004-100ML	04061837532078
271004-200L	04061838151810
271004-200L-P2-B	04061838151841
271004-20L-P2	04061838161376
271004-4X2L	04061826143582
271004-CH-200LP1KO	04061841232285
271004-PZ	04061823900706
271004-250ML	04061837532092
271004-12X100ML	04061837532085
271004-1L	04061826143575
271004-200L-P1	04061838151827
271004-2L	04061837532108
271004-50L-P2	04061838161383
271004-56L	04061836608644
271004-6X1L	04061837532115