234672
2,2′:6′,2′′-Terpyridine
98%, solid
동의어(들):
α,α′,α″-Tripyridyl, 2,6-Di(2-pyridyl)pyridine
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C15H11N3
CAS 번호:
Molecular Weight:
233.27
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
214-559-5
MDL number:
Beilstein/REAXYS Number:
11199
Assay:
98%
Form:
solid
제품 이름
2,2′:6′,2′′-Terpyridine, 98%
Quality Level
assay
98%
form
solid
mp
89-91 °C (lit.)
SMILES string
c1ccc(nc1)-c2cccc(n2)-c3ccccn3
InChI
1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H
InChI key
DRGAZIDRYFYHIJ-UHFFFAOYSA-N
General description
2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps, starting with 2-acetylpyridine. It coordinates with metal centers to form complexes. It is also utilized in the synthesis of chiral derivatives for asymmetric catalysis.
Application
Due to the presence of three near-coplanar nitrogen donor atoms, 2,2′:6′,2′′;-terpyridine may be used as a metal-binding domain to form metallo-supramolecular structures.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
저장 등급
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
2, 2?: 6?, 2 ?-Terpyridines: From chemical obscurity to common supramolecular motifs
Constable EC
Chemical Society Reviews, 36(2), 246-253 (2007)
An improved, two-step synthesis of 2, 2?: 6?, 2 ?-terpyridine
Jameson DL & Guise LE
Tetrahedron Letters, 32(18), 1999-2002 (1991)
2, 2': 6', 2'-Terpyridine.
Potts KT, et al.
Organic Syntheses, 189-189 (1986)
국제 무역 품목 번호
| SKU | GTIN |
|---|---|
| 234672-1G | 04061838784629 |
| 234672-250MG | 04061832747590 |
| 234672-5G | 04061838784636 |