콘텐츠로 건너뛰기
Merck

주요 문서

모든 문서 보기

912883

tBuBrettPhos Pd G6 TES

powder

동의어(들):

tBuBrettPhos OAC precatalyst TES

조직 및 계약 가격을 보려면 로그인를 클릭합니다.

크기 선택

보기 변경

제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
C43H66BrO4PPdSi
CAS 번호:
2097600-19-4
Molecular Weight:
892.37
MDL number:
MFCD34789852
UNSPSC Code:
12352100
NACRES:
NA.22
기술 서비스
도움이 필요하신가요? 저희 숙련된 과학자 팀이 도와드리겠습니다.
도움 문의

제품 이름

tBuBrettPhos Pd G6 TES,

Quality Level

100

product line

Buchwald precatalyst Generation 6

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

[Pd](Br)c3ccc(cc3)C(=O)OCC[Si](C)(C)C.P(C(C)(C)C)(C(C)(C)C)c1c(ccc(c1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC)OC

InChI key

ZIQMRJCMTGYLPQ-UHFFFAOYSA-M

Application

tBuBrettPhos Pd G6 TES is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Base

저장 등급

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our 문서 section.

도움이 필요하시면 연락하세요. 고객 지원 부서

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

문서

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

관련 콘텐츠

유기 반응 툴박스

유기 반응 툴박스는 고유한 화학 반응을 위한 구조 활성(structure-activity) 관계를 제공하여 소형 분자 합성을 최적적으로 디자인하고 조절합니다.

Organic Reaction Toolbox

An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.

Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Bases.
Xu J, et al.
ACS Catalysis, 9(7), 6461-6466 (2019)
Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

국제 무역 품목 번호

SKUGTIN
912883-100MG04061841784159
912883-1G04061841784166