909181
2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate
powder
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C25H26BF4N
CAS 번호:
Molecular Weight:
427.29
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
제품 이름
2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate,
form
powder
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
SMILES string
[B-](F)(F)(F)F.[n+]1(c2c(c(c4c1ccc(c4)C)c3c(cc(cc3C)C)C)cc(cc2)C)C
InChI key
UCBSHEKJRRAYNP-UHFFFAOYSA-N
Application
Robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
관련 콘텐츠
Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.
Nicewicz lab focuses on reactive cation radical species for selective reactions, advancing synthesis methodologies for various functional groups.
Dale J Wilger et al.
Nature chemistry, 6(8), 720-726 (2014-07-24)
The direct anti-Markovnikov addition of strong Brønsted acids to alkenes remains an unsolved problem in synthetic chemistry. Here, we report an efficient organic photoredox catalyst system for the addition of HCl, HF and also phosphoric and sulfonic acids to alkenes