908762
5,5′-Bis(trifluoromethyl)-2,2′-bipyridine
≥95%, powder or crystals
동의어(들):
5,5′-dCF3bpy
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크기 선택
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제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C12H6F6N2
CAS 번호:
Molecular Weight:
292.18
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Assay:
≥95%
Form:
powder or crystals
제품 이름
5,5′-Bis(trifluoromethyl)-2,2′-bipyridine, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
mp
129-130 °C
SMILES string
FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F
InChI
1S/C12H6F6N2/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18/h1-6H
InChI key
ZHMXQYAUGQASQM-UHFFFAOYSA-N
Application
5,5′-Bis(trifluoromethyl)-2,2′-bipyridine is a ligand used for the preparation of Ir(III) photocatalysts.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 3 Oral
저장 등급
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Gilbert J Choi et al.
Nature, 539(7628), 268-271 (2016-11-04)
Despite advances in hydrogen atom transfer (HAT) catalysis, there are currently no molecular HAT catalysts that are capable of homolysing the strong nitrogen-hydrogen (N-H) bonds of N-alkyl amides. The motivation to develop amide homolysis protocols stems from the utility of
Timothy M Monos et al.
Science (New York, N.Y.), 361(6409), 1369-1373 (2018-09-29)
Alkene aminoarylation with a single, bifunctional reagent is a concise synthetic strategy. We report a catalytic protocol for the addition of arylsulfonylacetamides across electron-rich alkenes with complete anti-Markovnikov regioselectivity and excellent diastereoselectivity to provide 2,2-diarylethylamines. In this process, single-electron alkene