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Merck

908568

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6

≥95%, powder or crystals

동의어(들):

[5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
C36H16F22IrN4P
CAS 번호:
Molecular Weight:
1145.69
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
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제품 이름

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

>300 °C

photocatalyst activation

460 nm

SMILES string

[Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F

InChI

1S/C12H6F6N2.2C12H5F5N.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-7(2,3,4,5)6;/h1-6H;2*1-2,4-6H;;/q;;;-1;+1

InChI key

QEXYETWHTSSWGM-UHFFFAOYSA-N

Application

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)


저장 등급

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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시험 성적서(COA)

Lot/Batch Number

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유기 반응 툴박스는 고유한 화학 반응을 위한 구조 활성(structure-activity) 관계를 제공하여 소형 분자 합성을 최적적으로 디자인하고 조절합니다.

An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.


Gilbert J Choi et al.
Nature, 539(7628), 268-271 (2016-11-04)
Despite advances in hydrogen atom transfer (HAT) catalysis, there are currently no molecular HAT catalysts that are capable of homolysing the strong nitrogen-hydrogen (N-H) bonds of N-alkyl amides. The motivation to develop amide homolysis protocols stems from the utility of
Timothy M Monos et al.
Science (New York, N.Y.), 361(6409), 1369-1373 (2018-09-29)
Alkene aminoarylation with a single, bifunctional reagent is a concise synthetic strategy. We report a catalytic protocol for the addition of arylsulfonylacetamides across electron-rich alkenes with complete anti-Markovnikov regioselectivity and excellent diastereoselectivity to provide 2,2-diarylethylamines. In this process, single-electron alkene