904767
[Ru(phen)3]Cl2
≥95%, powder or crystals
동의어(들):
Dichlorotris(1,10-phenanthroline)ruthenium(II) chloride
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크기 선택
보기 변경
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C36H24Cl2N6Ru
CAS 번호:
Molecular Weight:
712.59
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
제품 이름
[Ru(phen)3]Cl2, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
SMILES string
[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]
InChI
1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
InChI key
UWXWBVKIJZGXQL-UHFFFAOYSA-L
Application
[Ru(phen)3]Cl2 is a cyclometalated ruthenium complex that can be used in visible light mediated photocatalytic organic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
관련 콘텐츠
유기 반응 툴박스는 고유한 화학 반응을 위한 구조 활성(structure-activity) 관계를 제공하여 소형 분자 합성을 최적적으로 디자인하고 조절합니다.
An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.
Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Chelsea A Huff et al.
The Journal of organic chemistry, 81(16), 6980-6987 (2016-06-18)
We report the development of a method for room-temperature C-H hydroxymethylation of heteroarenes. A key enabling advance in this work was achieved by implementing visible light photoredox catalysis that proved to be applicable to many classes of heteroarenes and tolerant
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the