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Merck

904694

Ir(p-CF3-ppy)3

≥95%, powder or crystals

동의어(들):

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium

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제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
C36H21F9IrN3
CAS 번호:
Molecular Weight:
858.77
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
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제품 이름

Ir(p-CF3-ppy)3, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

[Ir]741([NH]8=C(c9c7cc(cc9)C(F)(F)F)C=CC=C8)([NH]5=C(c6c4cc(cc6)C(F)(F)F)C=CC=C5)[NH]2=C(c3c1cc(cc3)C(F)(F)F)C=CC=C2

InChI

1S/3C12H7F3N.Ir/c3*13-12(14,15)10-6-4-9(5-7-10)11-3-1-2-8-16-11;/h3*1-4,6-8H;

InChI key

ZLVNAIXHGHEODI-UHFFFAOYSA-N

Application

This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)


저장 등급

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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시험 성적서(COA)

Lot/Batch Number

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관련 콘텐츠

유기 반응 툴박스는 고유한 화학 반응을 위한 구조 활성(structure-activity) 관계를 제공하여 소형 분자 합성을 최적적으로 디자인하고 조절합니다.

An organic reaction toolbox provides structure-activity relationships for unique chemical reactions to optimally design and control small molecule synthesis.

Photoredox catalysis utilizes photocatalysts in the presence of visible light to form an array of synthetic transformations including, but not limited to, cross-coupling, C-H functionalization, alkene and arene functionalization, and trifluoromethylation.


A Singh et al.
Chemical science, 6(12), 7206-7212 (2015-12-01)
C-F functionalizations that provide C-C bonds are challenging synthetic transformations, due in part to the large C-F bond strength, short bond length, nonpolarizable nature, the production of fluoride, and the regioselectivity-in the case of multifluorinated substrates. However, commercially available highly
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)