746959
Ethenesulfonyl fluoride
95%
동의어(들):
ESF, Vinyl sulfonyl fluoride
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C2H3FO2S
CAS 번호:
Molecular Weight:
110.11
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22
Quality Level
분석
95%
양식
liquid
반응 적합성
reaction type: click chemistry
refractive index
n20/D 1.385
density
1.328 g/mL at 25 °C
SMILES string
O=S(F)(C=C)=O
InChI
1S/C2H3FO2S/c1-2-6(3,4)5/h2H,1H2
InChI key
BYPHZHGVWNKAFC-UHFFFAOYSA-N
일반 설명
Ethenesulfonylfluoride is a Michael acceptor used in dyestuffs, functional materials,photoresist materials, lubricating oil additives, and medicinal chemistry. Itexhibits extraordinary reactivity in SuFEx click chemistry and organicsynthesis.
애플리케이션
Ethenesulfonyl fluoride can be used as a reactant to synthesize:
- β-Arylethenesulfonyl fluorides via palladium(II) acetate-catalyzed Heck-Matsuda reaction with arenediazonium tetrafluoroborates.
- Bisalkylsulfonyl fluoride(BSF) monomers via Michael addition reaction with amines/anilines. BSF monomers are applicable in the synthesis of polysulfonates.
- Cyclobutane-fused pyridinyl sulfonyl fluorides by photocatalytic [2 + 2] cycloaddition with pyridones or isoquinolones.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
104.0 °F - closed cup
Flash Point (°C)
40 °C - closed cup
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문서
In collaboration with K. Barry Sharpless and coworkers, we offer a variety of sulfonyl fluoride reagents that undergo a “Click II” reaction.
관련 콘텐츠
The Sharpless Lab pursues useful new reactivity and general methods for selectively controlling chemical reactions.
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