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688096

Tris[2-phenylpyridinato-C2,N]iridium(III)

97%

동의어(들):

Ir(ppy)3, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]

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제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
C33H24IrN3
CAS 번호:
94928-86-6
Molecular Weight:
654.78
NACRES:
NA.23
PubChem Substance ID:
329760833
UNSPSC Code:
12352103
MDL number:
MFCD12022527
기술 서비스
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도움 문의

Quality Level

100

description

fac-Tris[2-phenylpyridinato-C2,N]iridium(III), Emissive Layer

assay

97%

form

powder

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

photocatalyst activation

425 nm

fluorescence

λex 340 nm; λem 512 nm in chloroform

orbital energy

HOMO 5.6 eV , LUMO 3 eV 

OLED device performance

ITO/HMPD/TAZ:Ir(ppy)3 (7%)/Alq3/Al:Li

  • Color: green
  • Max. Luminance: 4000 Cd/m2
  • Max. EQE: 15 %
, ITO/NPD/CBP:Ir(ppy)3 (6%)/Alq3/Mg:Ag
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
, ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
, ITO/TCTA/Ir(ppy)3/Bphen/LiF/Al
  • Color: green
  • Max. Luminance: 300000 Cd/m2
  • Max. EQE: 19 %
  • Turn-On Voltage: 2.6 V

SMILES string

c1ccc(nc1)-c2ccccc2[Ir](c3ccccc3-c4ccccn4)c5ccccc5-c6ccccn6

InChI

1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;

InChI key

QKBWDYLFYVXTGE-UHFFFAOYSA-N

General description

Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Application

Learn More at the Professor and Product Portal of Professor Corey Stephenson.
Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were also achieved with this catalyst.

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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저장 등급

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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시험 성적서(COA)

Lot/Batch Number
06323JH

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Organic Semiconductor Laser Materials

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관련 콘텐츠

Product Information Sheet - 688096

Spectra

Acta Volume 49 Number 3

Journal

Stephenson Group – Professor Product Portal

Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

Theoretical study on the absorption spectra of fac-Ir (ppy) 3 in the amorphous phase of organic electro-luminescent devices.
Asada T, et al.
Research on Chemical Intermediates, 35(8-9), 851-863 (2009)
Tuning the emission of cyclometalated iridium complexes by simple ligand modification
Ifor DW, et al.
Journal of Materials Chemistry, 13(1), 80-83 (2003)
High-efficiency, low-voltage phosphorescent organic light-emitting diode devices with mixed host
Kondakova, M.; Pawlik, T.; Young, R.; et al.
Journal of Applied Physics, 104, 094501-094501 (2008)
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688096-250MG04061832764702