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Merck

682373

Hoveyda-Grubbs Catalyst® M721

Umicore, solid

동의어(들):

Hoveyda-Grubbs Catalyst® M72 SI(o-Tol) (C571), Dichloro[1,3-bis(2-methylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II), Stewart-Grubbs catalyst

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제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
C27H30Cl2N2ORu
CAS 번호:
Molecular Weight:
570.52
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
기술 서비스
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제품 이름

Hoveyda-Grubbs Catalyst® M721, Umicore

Quality Level

product line

Grubbs Catalyst® M700 Series

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Ring-Opening Polymerization

manufacturer/tradename

Umicore Grubbs Catalyst® M700 Series

mp

199-208 °C

storage temp.

2-8°C

SMILES string

CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3ccccc3C)c4ccccc4C

InChI

1S/C17H18N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZDJCARGGZRTYFH-UHFFFAOYSA-L

Application

Less sterically hindered analog of Hoveyda-Grubbs Catalyst® 2nd Generation. Excels at ring-closing metathesis reactions of sterically encumbered olefins. Also useful for the cross metathesis of olefins bearing large allylic substituents.

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG


저장 등급

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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시험 성적서(COA)

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문서 라이브러리 방문


관련 콘텐츠

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

Olefin metathesis involves an organic reaction that redistributes fragments of alkenes (olefins) by cleavage and transformation of carbon-carbon double bonds.

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.


David E White et al.
Journal of the American Chemical Society, 130(3), 810-811 (2008-01-01)
Described in this report is the first total synthesis of elatol, a halogenated sesquiterpene in the chamigrene natural product family. The key disconnections in our synthetic approach include an enantioselective decarboxylative allylation to form the all-carbon quaternary stereocenter and a
Ian C Stewart et al.
Organic letters, 9(8), 1589-1592 (2007-03-24)
[reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ortho-substituted phenyl (e.g., tolyl). These new catalysts offer an exceptional increase in
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)



국제 무역 품목 번호

SKUGTIN
682373-100MG04061832754970
682373-2G04061833555101
682373-500MG04061832754987