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Merck

517135

Diethyl carbonate

greener alternative

anhydrous, ≥99%

동의어(들):

Diatol, Eufin, H-DEC

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
(C2H5O)2CO
CAS 번호:
Molecular Weight:
118.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-311-1
Beilstein/REAXYS Number:
956591
MDL number:
Assay:
≥99%
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도움 문의


grade

anhydrous

Quality Level

vapor density

4.1 (vs air)

vapor pressure

10 mmHg ( 23.8 °C), 59 mmHg ( 37.8 °C)

assay

≥99%

greener alternative product characteristics

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

<0.002% water, <0.005% water (100 mL)

refractive index

n20/D 1.384 (lit.)

bp

126-128 °C (lit.)

mp

−43 °C (lit.)

solubility

water: insoluble

density

0.975 g/mL at 25 °C (lit.)

functional group

carbonate

greener alternative category

SMILES string

O=C(OCC)OCC

InChI

1S/C5H10O3/c1-3-7-5(6)8-4-2/h3-4H2,1-2H3

InChI key

OIFBSDVPJOWBCH-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is used as a greener reagent. Click here for more information.
Diethyl carbonate is an dialkylcarbonate. The synthesis of diethyl carbonate (DEC) from urea and ethanol has been investigated.

Application

Diethyl carbonate may be used in the following studies:
  • Synthesis of β-enamino esters.
  • Synthesis of carbamates and unsymmetrical alkyl carbonates, via reaction with aliphatic amines or alcohols by using a hybrid organic-inorganic material prepared by anchoring TBD to MCM-41 silica.
  • As solvent in ruthenium catalyzed direct functionalisation of arene C-H bonds by aryl halides.
  • To compose the commercial liquid electrolyte for lithium ion batteries.
  • Homogeneous alkoxycarbonylation of cellulose.

Features and Benefits

Greener chemical


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Warning

hcodes

Hazard Classifications

Flam. Liq. 3

저장 등급

3 - Flammable liquids

wgk

WGK 1

flash_point_f

77.0 °F - closed cup

flash_point_c

25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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문서 라이브러리 방문


문서

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

Ionic liquid electrolytes explored for rechargeable batteries' advancement; future IL development discussed.

모든 기사 보기

관련 콘텐츠

Green chemicals evaluation aligns with the 12 Principles of Green Chemistry, emphasizing resource efficiency and hazard reduction.


Zhiyuan Zeng et al.
Faraday discussions, 176, 95-107 (2015-01-20)
We study the lithiation of a Au electrode in an electrochemical liquid cell using transmission electron microscopy (TEM). The commercial liquid electrolyte for lithium ion batteries (1 M lithium hexafluorophosphate LiPF6 dissolved in 1 : 1 (v/v) ethylene carbonate (EC) and diethyl
Diethyl carbonate as a solvent for ruthenium catalysed C-H bond functionalisation.
Arockiam P, et al.
Green Chemistry, 11(11), 1871-1875 (2009)
Synthesis of diethyl carbonate by catalytic alcoholysis of urea.
Wang D, et al.
Fuel Processing Technology, 88(8), 807-812 (2007)



국제 무역 품목 번호

SKUGTIN
517135-100ML04061832541556
517135-1L04061832541563