[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Name: [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
Brand: ALDRICH

solid

동의어(들):

1,2-Ethylenebis(diphenylphosphine)nickel dichloride, Nickel 1,2-Bis(diphenylphosphino)ethane dichloride, [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride, dppeNiCl₂

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:

[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]NiCl₂

CAS 번호:

14647-23-5

Molecular Weight:

528.02

UNSPSC Code:

12161600

PubChem Substance ID:

24859721

NACRES:

NA.22

MDL number:

MFCD00013313

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속성

제품 이름

[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II),

form

solid

Quality Level

100

reaction suitability

core: nickel, reagent type: catalyst

mp

263-265 °C (lit.)

SMILES string

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key

XXECWTBMGGXMKP-UHFFFAOYSA-L

설명

Application

Reactant involved in:

Kumada catalyst-transfer polycondensation
Oxidation of carboranyl phosphine ligands
Synthesis of nickel-iron dithiolato hydrides
Ullmann reactions - homocoupling reactions

Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers

Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes