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205885

Palladium(II) chloride

99%, powder, ReagentPlus®

동의어(들):

Dichloropalladium, Palladium dichloride, Palladous chloride

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제품정보 (DICE 배송 시 비용 별도)

실험식(Hill 표기법):
Cl2Pd
CAS 번호:
7647-10-1
Molecular Weight:
177.33
NACRES:
NA.22
PubChem Substance ID:
24852359
UNSPSC Code:
12161600
EC Number:
231-596-2
MDL number:
MFCD00003558
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제품 이름

Palladium(II) chloride, ReagentPlus®, 99%

Quality Level

200

product line

ReagentPlus®

assay

99%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

678-680 °C (lit.)

density

4 g/mL at 25 °C (lit.)

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

General description

Palladium(II) chloride is a widely used starting material for preparing other palladium catalysts, reagents, and nanoparticles.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Palladium(II) chloride (PdCl2) can be used as a catalyst in the following processes:
  • PdCl2-CuCl2 catalytic system is used in the selective acetylation of 1o and 2o alkyl or aryl alcohols with vinyl acetate to prepare corresponding acetylated derivatives.
  • PdCl2–EDTA is used in the Suzuki cross-coupling reaction between aryl and heteroaryl halides with aryl(heteroaryl)boronic acids in water.
  • PdCl2-Cu(OAc)2 is used to synthesize polysubstituted pyrroles from phenethylamines via multiple deprotonations and deamination reactions.
  • PdCl2-PEG(300) is used in the Suzuki-Miyaura coupling reaction.
  • PdCl2-NaBH4 is used in the hydrogenation of carbon-carbon triple bonds to synthesize corresponding cis-alkenes in a polyethylene glycol-CH2Cl2 reaction medium.
  • PdCl2-(n-Bu)3N-NH4OOCH catalytic system is used in the synthesis of benzofurans via intramolecular Heck reaction.
For small-scale and high throughput uses, the product is also available as ChemBeads (919853)

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

저장 등급

13 - Non Combustible Solids

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시험 성적서(COA)

Lot/Batch Number
MKBB0270
55696TJ
95296MJ
S60505
02510HJ

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문서 라이브러리 방문

Pd-EDTA as an efficient catalyst for Suzuki-Miyaura reactions in water
Korolev DN and Bumagin NA
Tetrahedron Letters, 46(34), 5751-5754 (2005)
PEG (300)-PdCl2 promoted efficient and convenient Suzuki-Miyaura coupling of aryl chlorides with arylboronic acids
Yin Liang, et al.
Tetrahedron, 62(40), 9359-9364 (2006)
Tetrahedron, 62, 9339-9339 (2006)
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국제 무역 품목 번호

SKUGTIN
205885-100G04061833301425
205885-1G04061835515370
205885-25G04061835521241
205885-5G04061835554546