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205869

Palladium(II) acetate

98%, reagent grade, powder

동의어(들):

Pd(OAc)2, [Pd(OAc)2]3

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
Pd(OCOCH3)2
CAS 번호:
3375-31-3
Molecular Weight:
224.51
NACRES:
NA.22
PubChem Substance ID:
24852356
UNSPSC Code:
12161600
EC Number:
222-164-4
MDL number:
MFCD00012453
Beilstein/REAXYS Number:
6086766
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제품 이름

Palladium(II) acetate, reagent grade, 98%

grade

reagent grade

Quality Level

200

assay

98%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

General description

[Pd(OAc)2]3 is a palladium coordination complex and a heterogenous metal catalyst that is widely used in organic synthesis such as transmetalation, insertion, oxidative addition, direct homocoupling of aryl halides, Buchwald-Hartwig reaction of C-N bond formation, reduction of alkynes, and reductive elimination reactions. It is also employed as a starting material for the synthesis of other Pd(II) compounds as well as for the preparation of active palladium catalysts for Suzuki-Miyaura cross-coupling and C-H functionalization reactions.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
[Pd(OAc)2]3 can be used as a:
  • Catalyst for the regioselective anti-hydrochlorination of the terminal and internal alkynes.
  • Precursor to prepare a heterogeneous palladium complex catalyst for the Heck-Coupling reaction and Sonogashira cross-coupling reaction.

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

저장 등급

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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시험 성적서(COA)

Lot/Batch Number
MKAA0862
30596LJ
1404968
06704HJ
06903CJ

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관련 콘텐츠

Mark McLaughlin et al.
Organic letters, 8(15), 3311-3314 (2006-07-14)
[Structure: see text] An efficient regioselective method for the preparation of structurally diverse imidazopyridinones and benzoimidazolones starting from readily available and economical starting materials is described. High-yielding reductive alkylation of electron-deficient o-haloarylamines followed by treatment with inexpensive N-chlorosulfonyl isocyanate afforded
Wolfe, J. P.; Buchwald, S. L.
The Journal of Organic Chemistry, 62, 1264-1264 (1997)
Mark S Chen et al.
Journal of the American Chemical Society, 126(5), 1346-1347 (2004-02-05)
Sulfoxide ligation to Pd(II) salts is shown to selectively promote C-H oxidation versus Wacker oxidation chemistry and to control the regioselectivity in the C-H oxidation products. A catalytic method for the direct C-H oxidation of monosubstituted olefins to linear (E)-allylic
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국제 무역 품목 번호

SKUGTIN
205869-100G04061833301418
205869-10G04061835508556
205869-25G04061835521234
205869-2G04061835554539
205869-1G04061835554522