902217
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
≥95%, powder or crystals
Synonyme(s) :
Ir photocatalyst, Photocatalyst
Se connecter pour consulter les tarifs organisationnels et contractuels.
Sélectionner une taille de conditionnement
Changer de vue
A propos de cet article
Formule empirique (notation de Hill) :
C34H16F18IrN4P
Numéro CAS:
Poids moléculaire :
1045.68
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
Service technique
Besoin d'aide ? Notre équipe de scientifiques expérimentés est là pour vous.
Laissez-nous vous aiderNom du produit
Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
assay
≥95%
form
powder or crystals
reaction suitability
core: iridium, reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
photocatalyst activation
450 nm
SMILES string
[Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F
InChI key
UCNIZYCFAFBGQB-UHFFFAOYSA-N
Application
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Classe de stockage
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Faites votre choix parmi les versions les plus récentes :
Déjà en possession de ce produit ?
Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.
Gilbert J Choi et al.
Nature, 539(7628), 268-271 (2016-11-04)
Despite advances in hydrogen atom transfer (HAT) catalysis, there are currently no molecular HAT catalysts that are capable of homolysing the strong nitrogen-hydrogen (N-H) bonds of N-alkyl amides. The motivation to develop amide homolysis protocols stems from the utility of
Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a
Numéro d'article de commerce international
| Référence | GTIN |
|---|---|
| 902217-100MG | 04061838635457 |
| 902217-500MG | 04061838635464 |