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908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%, powder or crystals

Synonyme(s) :

[(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

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A propos de cet article

Formule empirique (notation de Hill) :
C42H42F8IrN4P
Numéro CAS:
808142-88-3
Poids moléculaire :
977.99
MDL number:
MFCD31707653
UNSPSC Code:
12352101
NACRES:
NA.22
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Nom du produit

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: iridium
reaction type: Photocatalysis

photocatalyst activation

450 nm

InChI key

SNWREQGMGVVZPS-UHFFFAOYSA-N

Application

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Decarboxylative sp3 C-N coupling via dual copper and photoredox catalysis

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Consulter la Bibliothèque de documents

Yufan Liang et al.
Nature, 559(7712), 83-88 (2018-06-22)
Over the past three decades, considerable progress has been made in the development of methods to construct sp2 carbon-nitrogen (C-N) bonds using palladium, copper or nickel catalysis1,2. However, the incorporation of alkyl substrates to form sp3 C-N bonds remains one
Yong Yao Loh et al.
Science (New York, N.Y.), 358(6367), 1182-1187 (2017-11-11)
Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install
Andrew G Capacci et al.
Nature chemistry, 9(11), 1073-1077 (2017-10-25)
Although the α-alkylation of ketones has already been established, the analogous reaction using aldehyde substrates has proven surprisingly elusive. Despite the structural similarities between the two classes of compounds, the sensitivity and unique reactivity of the aldehyde functionality has typically