Principaux documents

920223

3,6-Di-tert-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate

Name: 3,6-Di-<I>tert</I>-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate
Brand: ALDRICH

≥95%, powder or crystals

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A propos de cet article

Formule empirique (notation de Hill) :

C₃₆H₃₇BF₇N

Numéro CAS:

2363740-69-4

Poids moléculaire :

627.49

MDL number:

MFCD34602222

UNSPSC Code:

12352103

NACRES:

NA.22

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Propriétés

Nom du produit

3,6-Di-tert-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate, ≥95%

Quality Level

100

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

storage temp.

−20°C

SMILES string

B(F)(F)F.[F-].FC(F)(F)c1ccc(cc1)[n+]2c3c(c(c5c2cc(cc5)C(C)(C)C)c4c(cccc4C)C)ccc(c3)C(C)(C)C

InChI

1S/C36H37F3N.BF3.FH/c1-22-10-9-11-23(2)32(22)33-28-18-14-25(34(3,4)5)20-30(28)40(27-16-12-24(13-17-27)36(37,38)39)31-21-26(35(6,7)8)15-19-29(31)33;2-1(3)4;/h9-21H,1-8H3;;1H/q+1;;/p-1

InChI key

XITZTMKZLKVHKJ-UHFFFAOYSA-M

Description

Application

3,6-Di-tert-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate is a robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Nucleophilic Aromatic Substitution of Unactivated Fluoroarenes Enabled by Organic Photoredox Catalysis

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Nucleophilic Aromatic Substitution of Unactivated Fluoroarenes Enabled by Organic Photoredox Catalysis.

Vincent A Pistritto et al.

Journal of the American Chemical Society, 142(40), 17187-17194 (2020-09-29)

Nucleophilic aromatic substitution (SNAr) is a classical reaction with well-known reactivity toward electron-poor fluoroarenes. However, electron-neutral and electron-rich fluoro(hetero)arenes are considerably underrepresented. Herein, we present a method for the nucleophilic defluorination of unactivated fluoroarenes enabled by cation radical-accelerated nucleophilic aromatic

Numéro d'article de commerce international

Référence	GTIN
920223-100MG	04065265875240
920223-500MG	04065265875257