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900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

Name: 9-Mesityl-3,6-di-<I>tert</I>-butyl-10-phenylacridinium tetrafluoroborate
Brand: ALDRICH

≥95%, powder or crystals

Synonyme(s) :

3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate

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A propos de cet article

Formule empirique (notation de Hill) :

C₃₆H₄₀BF₄N

Numéro CAS:

1810004-87-5

Poids moléculaire :

573.51

MDL number:

MFCD31381908

UNSPSC Code:

12352005

NACRES:

NA.22

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Propriétés

Nom du produit

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate, ≥95%

Quality Level

100

assay

≥95%

form

powder or crystals

reaction suitability

core: acridinium, reagent type: catalyst
reaction type: Photocatalysis

mp

277.2 °C

photocatalyst activation

455 nm

SMILES string

[F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C

InChI

InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1

InChI key

YUNSHKYOOCWQRB-UHFFFAOYSA-N

Description

Application

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

Other Notes

Site-selective arene C-H amination via photoredox catalysis

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Contenu apparenté

Nicewicz Group – Prof. Product Portal

Nicewicz lab focuses on reactive cation radical species for selective reactions, advancing synthesis methodologies for various functional groups.

Acridinium-Based Photocatalysts: A Sustainable Option in Photoredox Catalysis.

Joshi-Pangu A, et al.

The Journal of Organic Chemistry, 81(16), 7244-7249 (2016)

Numéro d'article de commerce international

Référence	GTIN
900421-100MG	04061833244531