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86833

Sigma-Aldrich

Tetrabutylammonium phosphate monobasic

99% (T), powder, puriss

Synonym(s):

Tetrabutylammonium dihydrogen phosphate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS Number:
5574-97-0
Molecular Weight:
339.45
Beilstein/REAXYS Number:
5196532
EC Number:
226-947-1
MDL number:
MFCD00064526
UNSPSC Code:
12352116
PubChem Substance ID:
329769489
NACRES:
NA.21

Key Documents

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Product Name

Tetrabutylammonium phosphate monobasic, puriss., 99% (T)

grade

puriss.

Quality Level

100

assay

99% (T)

form

powder

mp

151-154 °C (lit.)

SMILES string

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

InChI key

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

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General description

Tetrabutylammonium phosphate monobasic is a synthetic reagent. It can serve as a pH buffer in various chemical and biological applications.

Application

Tetrabutylammonium phosphate monobasic is the suitable reagent used in the following studies:
  • Resolution of disaccharides reverse-phase ion-pairing HPLC (RPIP-HPLC).
  • Disaccharide analysis of 35S- heparan sulfate (HS).
  • As folding buffer for the dissolution of desalted oligonucleotides.
It may be used as reagent for the analysis of tetrasaccharides and 35S-disaccharides by HPLC. It may also be used in the preparation of monobasic tetrabutylammonium phosphate (TBAP) imprinted polymers.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH1184
BCCG8169
BCCG5619
BCCG3967
BCCF9998

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Vaibhav Tiwari et al.
Journal of virology, 80(18), 8970-8980 (2006-08-31)
Herpes simplex virus type 1 (HSV-1) infection of the corneal stroma remains a major cause of blindness. Primary cultures of corneal fibroblasts (CF) were tested and found susceptible to HSV-1 entry, which was confirmed by deconvolution imaging of infected cells.
Robert D Gray et al.
Nucleic acids research, 36(12), 4191-4203 (2008-06-24)
Cation-induced folding into quadruplex structures for three model human telomeric oligonucleotides, d[AGGG(TTAGGG)(3)], d[TTGGG(TTAGGG)(3)A] and d[TTGGG(TTAGGG)(3)], was characterized by equilibrium titrations with KCl and NaCl and by multiwavelength stopped flow kinetics. Cation binding was cooperative with Hill coefficients of 1.5-2.2 in
Polymerisable squaramide receptors for anion binding and sensing.
Manesiotis P, et al.
Journal of Material Chemistry C, 2(42), 8990-8995 (2014)
J Liu et al.
The Journal of biological chemistry, 274(53), 38155-38162 (1999-12-23)
3-O-Sulfation of glucosamine by heparan sulfate D-glucosaminyl 3-O-sulfotransferase (3-OST-1) is the key modification in anticoagulant heparan sulfate synthesis. However, the heparan sulfates modified by 3-OST-2 and 3-OST-3A, isoforms of 3-OST-1, do not have anticoagulant activity, although these isoforms transfer sulfate
Guoqing Xia et al.
The Journal of biological chemistry, 277(40), 37912-37919 (2002-07-26)
Heparan sulfate 3-O-sulfotransferase transfers sulfate to the 3-OH position of a glucosamine residue of heparan sulfate (HS) to form 3-O-sulfated HS. The 3-O-sulfated glucosamine residue contributes to two important biological functions of HS: binding to antithrombin and thereby carrying anticoagulant
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