901742
Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride
≥95%
Synonym(s):
(PyrNMeNN)Ni-Cl, (SP-4-4)-Chloro[N1,N1-dimethyl-N2-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN1,κN2]nickel, Second-generation Nickamine
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About This Item
Empirical Formula (Hill Notation):
C18H22ClN3Ni
Molecular Weight:
374.53
UNSPSC Code:
12352101
assay
≥95%
form
powder or crystals
reaction suitability
core: nickel, reagent type: catalyst
SMILES string
CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl
Application
As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions.
Franco TD, et al.
Helvetica Chimica Acta, 99(11), 830-847 (2016)
From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides.
Garcia PMP, et al.
ACS Catalysis, 6 (1), 258-261 (2016)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 901742-100MG | 04061835505135 |
| 901742-250MG | 04061835505043 |