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747807

CyJohnPhos Pd G2

solid

Synonym(s):

Chloro(2-dicyclohexylphosphino-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II), CyJohnPhos-G2, CyJohnPhos-Pd-G2

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About This Item

Empirical Formula (Hill Notation):
C36H41ClNPPd
CAS Number:
Molecular Weight:
660.56
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

CyJohnPhos Pd G2,

Quality Level

product line

Buchwald precatalyst Generation 2

form

solid

feature

generation 2

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

178-183 °C (decomposition without melting)

functional group

phosphine

SMILES string

NC1=CC=CC=C1C2=CC=CC=C2[Pd]Cl.P(C3CCCCC3)(C4=C(C5=CC=CC=C5)C=CC=C4)C6CCCCC6

InChI

1S/C24H31P.C12H10N.ClH.Pd/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1

InChI key

PLKOENXOQXWSIL-UHFFFAOYSA-M



Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Buchwald precatalysts and ligands are bulky electron-rich dialkylbiaryl phospine-based catalysts and structurally related ligands that improve reactivity in Pd-catalyzed cross - coupling reactions





Global Trade Item Number

SKUGTIN
747807-500MG04061832970370
747807-1G04061826251737