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668729

Diethylzinc

Name: Diethylzinc
Brand: ALDRICH

packaged for use in deposition systems

Synonym(s):

DEZn, Et₂Zn, DEZ, Zincdiethyl

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About This Item

Linear Formula:

(C₂H₅)₂Zn

CAS Number:

557-20-0

Molecular Weight:

123.51

UNSPSC Code:

12352103

NACRES:

NA.23

PubChem Substance ID:

24885000

EC Number:

209-161-3

Beilstein/REAXYS Number:

3587207

MDL number:

MFCD00009021

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Properties

Quality Level

100

form

liquid

refractive index

n20/D 1.498 (lit.)

bp

117 °C (lit.)

mp

−28 °C (lit.)

density

1.205 g/mL at 25 °C (lit.)

SMILES string

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChI key

HQWPLXHWEZZGKY-UHFFFAOYSA-N

Description

General description

Atomic number of base material: 30 Zinc

Application

Precursors Packaged for Depositions Systems

Reacted with water in a low temperature (<200°C) atomic layer deposition of polycrystalline ZnO layers displaying exciton photoluminescence at room temperature.

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pictograms

GHS02,GHS05,GHS09

signalword

Danger

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react. 1

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Certificates of Analysis (COA)

Lot/Batch Number

12803AJ

06431KH

06914JE

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Articles

Atomic Layer Deposition of Nanomaterials for Li-Ion Batteries, Fuel Cells, and Solar Cells

Nanomaterials are considered a route to the innovations required for large-scale implementation of renewable energy technologies in society to make our life sustainable.

Savannah ALD System for Atomic Layer Deposition

Atomic Layer Deposition (ALD) technology ensures uniform coating on complex 3D surfaces with precise chemisorption cycles.

Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

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Journal of Applied Physics, 103, 033515-033515 (2008)

The synthesis of new oxazoline-containing bifunctional catalysts and their application in the addition of diethylzinc to aldehydes.

Vincent Coeffard et al.

Organic & biomolecular chemistry, 7(8), 1723-1734 (2009-04-04)

The straightforward preparation of new modular oxazoline-containing bifunctional catalysts is reported employing a microwave-assisted Buchwald-Hartwig aryl amination as the key step. Covalent attachment of 2-(o-aminophenyl)oxazolines and pyridine derivatives generated in good-to-high yields a series of ligands in two or three

A green chemistry approach to a more efficient asymmetric catalyst: solvent-free and highly concentrated alkyl additions to ketones.

Sang-Jin Jeon et al.

Journal of the American Chemical Society, 127(47), 16416-16425 (2005-11-25)

There is a great demand for development of catalyst systems that are not only efficient and highly enantioselective but are also environmentally benign. Herein we report investigations into the catalytic asymmetric addition of alkyl and functionalized alkyl groups to ketones

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Global Trade Item Number

SKU	GTIN
668729-25G	04061838254146