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MilliporeSigma

403342

Sigma-Aldrich

Copper(I) acetate

97%

Synonym(s):

Copper monoacetate, Cuprous acetate

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About This Item

Linear Formula:
CuCO2CH3
CAS Number:
598-54-9
Molecular Weight:
122.59
EC Number:
209-938-7
MDL number:
MFCD00058908
UNSPSC Code:
12352103
PubChem Substance ID:
24865183
NACRES:
NA.23

Key Documents

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Quality Level

200

assay

97%

form

powder and chunks

reaction suitability

core: copper
reagent type: catalyst

mp

250 °C (dec.) (lit.)

SMILES string

CC(=O)O[Cu]

InChI

1S/C2H4O2.Cu/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

InChI key

RFKZUAOAYVHBOY-UHFFFAOYSA-M

Related Categories

General description

Copper(II) acetate hydrate is a high-purity (98%), blue crystalline solid widely used as a versatile precursor for copper-based materials. Its hydrate form enhances solubility in aqueous/organic solvents, facilitating solution processing for advanced applications. Recent research emphasizes its role in sustainable energy technologies, catalysis, and functional nanomaterials, aligning with trends in green chemistry and renewable energy.

Application

Copper(II) acetate hydrate can be used as:
  • A copper source in synthesizing CuS@C nanocomposites for sodium-ion battery anodes, delivering 485 mAh/g capacity after 200 cycles.
  • A precursor to synthesize copper oxide thin films through deposition techniques like atomic layer deposition (ALD) and pulsed spray pyrolysis, enabling p-type semiconductor layers for optoelectronic applications.
  • A electrocatalyst precursor for CO2 reduction to ethanol.
  • A Precursor for superhydrophobic coatings via electrochemical deposition.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP5472
MKCN4879
MKCL2120
MKCJ5676
MKCG9020

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Jan Lorkowski et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(48), 11365-11374 (2019-07-06)
Cyclic (amino)(aryl)carbenes (cAArCs) based on the isoindoline core were successfully generated in situ by α-elimination of 3-alkoxyisoindolines at high temperatures or by deprotonation of isoindol-2-ium chlorides with sodium or copper(I) acetates at low temperatures. 3-Alkoxy-isoindolines 2 a,b-OR (R=Me, Et, iPr) have
Qiuyan Jin et al.
European journal of mass spectrometry (Chichester, England), 25(1), 30-43 (2019-02-19)
Gas-phase ion trap mass spectrometry experiments and density functional theory calculations have been used to examine the routes to the formation of the 1,8-naphthyridine (napy) ligated geminally dimetallated phenyl complexes [(napy)Cu2(Ph)]+, [(napy)Ag2(Ph)]+ and [(napy)CuAg(Ph)]+ via extrusion of CO2 or SO2
Room?Temperature Formation of Hollow Cu2O Nanoparticles.
Hung LI, et al.
Advanced Materials, 22.17, 1910-1914 (2010)
Synthesis of delafossite CuAlO 2 p-type semiconductor with a nanoparticle-based Cu (I) acetate-loaded boehmite precursor
Thu TV, et al.
Mat. Res. Bul., 46.11, 1819-1827 (2011)
You Zhai et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 17(5), 741-751 (2015-11-04)
Cu2 S/ZnS heterostructured nanorods (HNRs) with uncommon morphologies are achieved through single-pot and multi-batch synthetic strategies. In both cases, Cu2 S NRs form first, which then undergo partial cation exchange and solution-liquid-solid (SLS)-like growth catalyzed by the remaining Cu2 S
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Articles

Group 11 Thin Films by Atomic Layer Deposition

Copper metal deposition processes are an essential tool for depositing interconnects used in microelectronic applications, giving group 11 (coinage metals: Copper, Silver, and Gold) an important place in atomic layer deposition (ALD) process development.

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