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723150

2-Hydroxyethyl 2-bromoisobutyrate

95%

Synonym(s):

ATRP hydroxy initiator, HEBIB, HO-BriBu

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About This Item

Empirical Formula (Hill Notation):
C6H11BrO3
CAS Number:
189324-13-8
Molecular Weight:
211.05
NACRES:
NA.23
PubChem Substance ID:
329763981
UNSPSC Code:
12162002
MDL number:
MFCD16621490
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Quality Level

100

assay

95%

form

liquid

refractive index

n20/D 1.476

density

1.456 g/mL at 25 °C

SMILES string

CC(C)(Br)C(=O)OCCO

InChI

1S/C6H11BrO3/c1-6(2,7)5(9)10-4-3-8/h8H,3-4H2,1-2H3

InChI key

MHXMVFDLNGKBSR-UHFFFAOYSA-N

Application

Atom Transfer Radical Polymerization (ATRP) initiator for the creation of hydroxy functionalized telechelic polymers. Can be used to modify carboxylate- or isocyanate- modified surfaces, particles or biomolecules.
ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

hcodes

H302,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Abhispa Sahu et al.
Ultrasonics sonochemistry, 67, 105163-105163 (2020-05-18)
This paper reports on sonochemically catalyzed atom transfer radical polymerization (SONO-ATRP) polyelectrolyte synthesis and chain-end functionalization to single-walled carbon nanotubes (SWCNT). This all aqueous process is kinetically facile without use of initiator, or reducing agents and with very low concentrations
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)
Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
View All Related Papers

Global Trade Item Number

SKUGTIN
723150-1G04061832861074
723150-5G04061832861081