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546461

MDMO-PPV

light-emitting polymer

Synonym(s):

Poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)-1,4-phenylenevinylene]

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About This Item

CAS Number:
177716-59-5
UNSPSC Code:
12352103
PubChem Substance ID:
24878898
NACRES:
NA.23
MDL number:
MFCD03458070
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description

Band gap: 2.2 eV

mol wt

Mn ~120,000

solubility

toluene, xylene, THF, chloroform, chlorobenzene, cyclohexanone: soluble

fluorescence

λex 485 nm; λem 555 nm in toluene

orbital energy

HOMO -5.4 eV , LUMO -3.2 eV 

OPV device performance

ITO/PEDOT:PSS/MDMO-PPV/PC61BM/Al

  • Short-circuit current density (Jsc): 0.96 mA/cm2
  • Open-circuit voltage (Voc): 0.78 V
  • Fill Factor (FF): 0.5
  • Power Conversion Efficiency (PCE): 0.5 %
, ITO/PEDOT:PSS/MDMO-PPV:PC61BM (1:4)/LiF/Al
  • Short-circuit current density (Jsc): 5.25 mA/cm2
  • Open-circuit voltage (Voc): 0.82 V
  • Fill Factor (FF): 0.61
  • Power Conversion Efficiency (PCE): 3.3 %

SMILES string

COc1ccc(OCCC(C)CCCC(C)C)cc1C=C

General description

MDMO-PPV is a dialkoxy substituted poly(p-phenylenevinylene) (PPV) based conjugating polymer which has long side chains that form flexible films for organic electronics. It is a piezoresistant polymer with HOMO and LUMO orbital positions at 5.4 and 3.4 eV, respectively. MDMO-PPV forms an active layer that can be used in photoconductive and electroluminescent applications. Its processability and film-forming properties are superior to MEH-PPV.

Application

MDMO-PPV can also be used in the fabrication of bulk heterojunction solar cells(BHJ).
MDMO-PPV can be blended with (6,6 phenyl C61- butyric acid methyl ester) (PCBM), which can be coated on indium tin oxide (ITO) to fabricate polymeric solar cells. It can also be used as a red light emitting polymer (LEP), which can be used in the fabrication of red-green-blue laser-based polymeric membranes.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
97896KJ
06113JH
04309KH
02216EE
08525DE

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Related Content

Wavelength (nm) 546461

Spectra

Advanced Applications of Engineered Nanomaterials

This thematic issue focuses on the emerging applications of nanomaterials. Nanomaterials are defined as substances with at least one dimension smaller than 100 nm.

Aging of a donor conjugated polymer: Photochemical studies of the degradation of poly [2-methoxy-5-(3?, 7?-dimethyloctyloxy)-1, 4-phenylenevinylene].
Chambon S, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 45(2), 317-331 (2007)
Stress-induced variation of MDMO-PPV film thickness and resistance.
Hou W, et al.
Synthetic Metals, 226(1-3), 113-118 (2017)
Barry C Thompson et al.
Angewandte Chemie (International ed. in English), 47(1), 58-77 (2007-11-29)
Fossil fuel alternatives, such as solar energy, are moving to the forefront in a variety of research fields. Polymer-based organic photovoltaic systems hold the promise for a cost-effective, lightweight solar energy conversion platform, which could benefit from simple solution processing
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Global Trade Item Number

SKUGTIN
546461-1G04061832573885
546461-250MG04061833238820