661384
2-Iodoxybenzoic acid
contains stabilizer, 45 wt. % (IBX)
Synonym(s):
SIBX, Stabilized IBX
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About This Item
Empirical Formula (Hill Notation):
C7H5IO4
CAS Number:
Molecular Weight:
280.02
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Level
contains
stabilizer
reaction suitability
reagent type: oxidant
concentration
45 wt. % (IBX)
functional group
iodo
SMILES string
OI1(=O)OC(=O)c2ccccc12
InChI
1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)
InChI key
CQMJEZQEVXQEJB-UHFFFAOYSA-N
Related Categories
Application
A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.
Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.
Other Notes
The material is stabilized with benzoic acid and isophthalic acid
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3
Target Organs
Lungs, Respiratory system
Supplementary Hazards
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Aurélie Ozanne et al.
Organic letters, 5(16), 2903-2906 (2003-08-02)
[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use
Roberta Bernini et al.
Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)
A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate
Synthetic Communications, 37, 3493-3493 (2007)
Celine L Hartman et al.
Journal of lipid research, 59(1), 113-122 (2017-11-24)
Endothelial dysfunction is a hallmark of multiple inflammatory diseases. Leukocyte interactions with the endothelium have significant effects on vascular wall biology and pathophysiology. Myeloperoxidase (MPO)-derived oxidant products released from leukocytes are potential mediators of inflammation and endothelial dysfunction. 2-Chlorofatty acids
Jane McHowat et al.
Frontiers in physiology, 11, 460-460 (2020-05-28)
Endothelial activation and dysfunction are hallmarks of inflammation. Neutrophil-vascular endothelium interactions have significant effects on vascular wall physiology and pathology. Myeloperoxidase (MPO)-derived products released from activated neutrophils can mediate the inflammatory response and contribute to endothelial dysfunction. 2-Chlorofatty aldehyde (2-ClFALD)
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