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Merck

T6381

N,O-Bis(trimethylsilyl)trifluoroacetamide with trimethylchlorosilane

with 1% trimethylchlorosilane, derivatization grade (GC derivatization), LiChropur

동의어(들):

BSTFA + TMCS

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
CF3C[=NSi(CH3)3]OSi(CH3)3
CAS 번호:
Molecular Weight:
257.40
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2050024
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grade

derivatization grade (GC derivatization)

Quality Level

quality

LiChropur, with 1% trimethylchlorosilane

contains

1% trimethylchlorosilane as additive

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

technique(s)

gas chromatography (GC): suitable

color

hazy clear to colorless

refractive index

n20/D 1.384 (lit.)

bp

45-50 °C/14 mmHg (lit.)

solubility

hexane: miscible 100 mg/mL

density

0.97 g/mL (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+

InChI key

XCOBLONWWXQEBS-KPKJPENVSA-N

General description

N,O-Bis(trimethylsilyl)trifluoroacetamide with trimethylchlorosilane is a silylating reagent generally used in estrogenic steroid hormone identification and quantification.

Application

BSTFA+TMCS has been used as derivatizing reagent for GC-MS determination of natural and synthetic estrogenic steroids.

Packaging

Clear borosilicate glass, high hydrolytic resistance (Type I)
Sealed ampules contain 1 ml. Gram sizes are in screw-cap bottles.

Other Notes

The position of the silyl groups has not been unequivocally established. It has been referred to as both N,N and N,O.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany


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Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

저장 등급

3 - Flammable liquids

wgk

WGK 3

flash_point_f

44.1 °F - closed cup

flash_point_c

6.7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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문서 라이브러리 방문



Pitfalls and solution for simultaneous determination of estrone and 17a-ethinylestradiol by gas chromatography?mass spectrometry after derivatization with N, O-bis (trimethylsilyl) trifluoroacetamide.
Zhang, Kai, and Yuegang Zuo.
Analytica Chimica Acta, 554.1, 190-196 (2005)
Ahmed I Rushdi et al.
SpringerPlus, 3, 253-253 (2014-06-14)
Propolis is a sticky material mixed by honeybees to utilize it in protecting their hives from infection by bacteria and fungi. The therapeutic properties of propolis are due to its chemical composition with bio-active compounds; therefore, researchers are interested in
Hidenori Matsukami et al.
The Science of the total environment, 493, 672-681 (2014-07-06)
Chlorinated and non-halogenated organophosphorus flame retardants (OPFRs) including tris(2-chloroisopropyl) phosphate (TCIPP), diethylene glycol bis(di(2-chloroisopropyl) phosphate) (DEG-BDCIPP), triphenyl phosphate (TPHP), and bisphenol A bis(diphenyl phosphate) (BPA-BDPP) have been used increasingly as alternatives to polybrominated diphenyl ethers and other brominated flame retardants.



국제 무역 품목 번호

SKUGTIN
T6381-100G04061837688638
T6381-1AMP04061837688652
T6381-10AMP04061837688645
T6381-25G04061837688676
T6381-5G04061837688683