39405
4-(Dimethylamino)pyridine
purum, ≥98.0% (NT)
동의어(들):
N,N-Dimethylpyridin-4-amine, DMAP
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C7H10N2
CAS 번호:
Molecular Weight:
122.17
Beilstein:
110354
EC Number:
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22
grade
purum
Quality Level
분석
≥98.0% (NT)
양식
crystals
pellets
mp
108-110 °C (lit.)
111-114 °C
solubility
methanol: 0.1 g/mL, clear, colorless to almost colorless
작용기
amine
SMILES string
CN(C)c1ccncc1
InChI
1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3
InChI key
VHYFNPMBLIVWCW-UHFFFAOYSA-N
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일반 설명
4-(Dimethylamino)pyridine is generally employed as a catalyst in the acylation of amines, alcohols, enolates, and phenols. It can also be used in the esterification of carboxylic acids. It is known to exhibit good catalytic activity in non-polar solvents.
애플리케이션
4-(Dimethylamino)pyridine can be used:
- As a capping agent in the preparation of water-soluble gold nanoparticles.
- As an initiator in the polymerization of epoxy monomers.
- As an auxiliary reagent in the electroless preparation of gold nanotubes applicable in catalysis.
- As a catalyst in the preparation of γ- and δ-lactones via iodolactonization of γ,δ-unsaturated carboxylic acids.
A highly efficient catalyst for acylation reactions
기타 정보
Hypernucleophilic acylation catalyst.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1
표적 기관
Nervous system
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
255.2 °F
Flash Point (°C)
124 °C
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A. Hassner
Tetrahedron, 34, 2069-2069 (1978)
E.F. Scriben
Chemical Society Reviews, 13, 129-129 (1983)
Hoefle, G., et al.
Angewandte Chemie (International Edition in English), 90, 602-602 (1978)
Giovanna Cutrone et al.
Carbohydrate polymers, 223, 115085-115085 (2019-08-21)
Nanoparticles made of metal-organic frameworks (nanoMOFs) are becoming of increasing interest as drug carriers. However, engineered coatings such as poly(ethylene glycol) (PEG) based ones are required to prevent nanoMOFs recognition and clearance by the innate immune system, a prerequisite for
Yi Zhang et al.
ACS applied materials & interfaces, 11(50), 46427-46436 (2019-11-26)
A kind of specific cyclodextrin polyrotaxanes (PRs) drug delivery system was developed for an effective drug delivery and enhancing antitumor effect. In this work, we prepared the PR by using α-CD derivatives and dicarboxyl-PEG (Mn = 4200) self-assembling and end-capping
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