132934
Aniline
99%, liquid, suitable for synthesis, ReagentPlus®
동의어(들):
Aminobenzene, Benzenamine
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
C6H5NH2
CAS 번호:
Molecular Weight:
93.13
Beilstein:
605631
EC Number:
MDL number:
UNSPSC 코드:
12352100
eCl@ss:
39030407
PubChem Substance ID:
NACRES:
NA.21
Bp:
184 °C (lit.)
Vapor pressure:
0.7 mmHg ( 25 °C)
제품 이름
Aniline, ReagentPlus®, 99%
vapor density
3.22 (185 °C, vs air)
Quality Level
vapor pressure
0.7 mmHg ( 25 °C)
제품 라인
ReagentPlus®
분석
99%
양식
liquid
autoignition temp.
1139 °F
expl. lim.
11 %
dilution
(for general lab use)
refractive index
n20/D 1.586 (lit.)
pH
8.8 (20 °C, 36 g/L)
bp
184 °C (lit.)
mp
−6 °C (lit.)
solubility
water: soluble
density
1.022 g/mL at 25 °C (lit.)
SMILES string
Nc1ccccc1
InChI
1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
InChI key
PAYRUJLWNCNPSJ-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
일반 설명
Aniline is an aromatic amine. It is a key industrial intermediate, widely employed for the preparation of dyes, rubber, resins and polymers. Complete vibrational assignements of aniline and its deuterated forms (aniline-NHD and aniline-ND2) have been reported.1 p-aminodiphenylamine (ADPA) has been reported to be formed as a major intermediate during the electropolymerizatrion of aniline. Its viscosity has been reported to be 3.1457cp at 30°C. Quantitative transformation of nitrobenzene to aniline has been carried out by employing functionalized plasmonic Au/TiO2 photocatalyst along with a Ag co-catalyst. Aniline can be prepared from nitrobenzene, via hydrogenation in the presence of Cu, Ni, Pt, Pd and Au (catalyst). It can also be prepared by photocatalytic reduction of nitrobenzene in the presence of WO3-Ag hybrid nanowires.
Material darkens in storage to reddish-brown with no loss in purity.
애플리케이션
Aniline may be used in the preparation of azobenzene.
생화학적/생리학적 작용
The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and the accumulation of methemoglobin and the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration.
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1
표적 기관
Blood
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point (°F)
158.0 °F - closed cup
Flash Point (°C)
70 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
The application of fast scan cyclic voltammetry. Mechanistic study of the initial stage of electropolymerization of aniline in aqueous solutions.
Yang H and Bard AJ.
Journal of Electroanalytical Chemistry, 339(1), 423-449 (1992)
Viscosities of Binary Mixtures of Benzyl Acetate with Dioxane, Aniline, and m-Cresol.
Katti PK and Chaudhri MM.
Journal of Chemical and Engineering Data, 9(3), 442-443 (1964)
Atsuhiro Tanaka et al.
Chemical communications (Cambridge, England), 49(25), 2551-2553 (2013-02-21)
A functionalized plasmonic Au/TiO2 photocatalyst with an Ag co-catalyst was successfully prepared by the combination of two types of photodeposition methods, and it quantitatively converted nitrobenzene and 2-propanol to aniline and acetone under irradiation of visible light.
Photocatalytic hydrogenation of nitrobenzene to aniline over tungsten oxide-silver nanowires.
Fu L, et al.
Materials Letters, 142, 201-203 (2015)
Abdessamad Grirrane et al.
Nature protocols, 5(3), 429-438 (2010-03-06)
This protocol describes the aerobic oxidation of aromatic anilines to aromatic azo compounds using gold (Au) nanoparticles supported on TiO(2) as a catalyst. Yields above 98% are achieved under a few bars of oxygen pressure. It should be noted that
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.