114189
Acetyl chloride
reagent grade, 98%, liquid
동의어(들):
Acetic acid chloride, Acetic chloride, Ethanoyl chloride
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH3COCl
CAS 번호:
Molecular Weight:
78.50
Beilstein:
605303
EC Number:
MDL number:
UNSPSC 코드:
12352100
eCl@ss:
39050501
PubChem Substance ID:
NACRES:
NA.21
제품 이름
Acetyl chloride, reagent grade, 98%
Grade
reagent grade
Quality Level
vapor density
2.7 (vs air)
vapor pressure
11.69 psi ( 20 °C)
32.33 psi ( 55 °C)
분석
98%
양식
liquid
autoignition temp.
1353 °F
expl. lim.
19 %
refractive index
n20/D 1.389 (lit.)
bp
52 °C (lit.)
mp
−112 °C (lit.)
density
1.104 g/mL at 25 °C (lit.)
작용기
acyl chloride
SMILES string
CC(Cl)=O
InChI
1S/C2H3ClO/c1-2(3)4/h1H3
InChI key
WETWJCDKMRHUPV-UHFFFAOYSA-N
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일반 설명
Acetyl chloride is used as an acylating reagent for electrophilic acetylation of alkynes, alkenes, arenes, saturated alkanes, enolates, and organometallics.
Acetyl chloride is a colorless acyl halide. On reaction with ammonia and alcohols, it affords acetamide and esters of acetic acid, respectively. Structural parameters and rotational constants of its isotopic forms have been evaluated from the microwave spectral investigations.
Acetyl chloride is a colorless acyl halide. On reaction with ammonia and alcohols, it affords acetamide and esters of acetic acid, respectively. Structural parameters and rotational constants of its isotopic forms have been evaluated from the microwave spectral investigations.
애플리케이션
Acetyl chloride has been used in the Lepage and Roy fatty acids analysis, and robotic fatty acid analysis. It may be used for the qualitative in situ synthesis of hydrogen chloride.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
41.0 °F - closed cup
Flash Point (°C)
5 °C - closed cup
Yu Hong Lin et al.
Lipids, 47(5), 527-539 (2012-03-21)
Large population studies show that polyunsaturated fatty acids are important for human health, but determining relationships between the health benefits and the fatty acid content has been hampered by the unavailability of labor-effective high-throughput technologies. An automated high throughput fatty
Microwave spectrum of acetyl chloride.
Sinnott, KM.
J. Chem. Phys. , 34(3), 851-861 (1961)
Acetyl Chloride-Methanol as a Convenient Reagent for: A) Quantitative Formation of Amine Hydrochlorides B) Carboxylate Ester Formation C) Mild Removal of Nt-Boc-Protective Group.
Nudelman A, et al.
Synthetic Communications, 28(3), 471-474 (1998)
Eagleson M.
Concise Encyclopedia Chemistry, 4-4 (1994)
Yu-Ting Liu et al.
The journal of physical chemistry. A, 114(27), 7275-7283 (2010-06-24)
In one-photon dissociation of gaseous acetyl chloride at 248 nm, time-resolved Fourier-transform infrared emission spectroscopy is used to detect the fragments of HCl, CO, and CH(2) in the presence of Ar or O(2). The high-resolution spectra of HCl and CO
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