F408
Ferrocene
98%
동의어(들):
Bis(cyclopentadienyl)iron, Di(cyclopentadienyl)iron
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
Fe(C5H5)2
CAS 번호:
Molecular Weight:
186.03
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
vapor pressure
0.03 mmHg ( 40 °C)
Quality Level
분석
98%
반응 적합성
core: iron
reagent type: catalyst
bp
249 °C (lit.)
mp
172-174 °C (lit.)
λmax
358 nm
저장 온도
2-8°C
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;
InChI key
DFRHTHSZMBROSH-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Ferrocene (dicyclopentadienyliron) can be used:
- As a scaffold for chiral ligands in asymmetric catalysis.
- In ferrocene-based electrolytes for dye sensitized solar cells applications.
- In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.
- In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.
- In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).
- In the preparation of ferrocenium salt which is used as a mild oxidant.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation
표적 기관
Liver
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
Atkinson RCJ, et al.
Chemical Society Reviews, 33(33), 313-328 (2004)
Muneebah Adams et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4677-4685 (2013-01-31)
A series of aryl-functionalized and ferrocenyl monothiosemicarbazone compounds (L1-L4) were synthesized in moderate yields via a general Schiff-base condensation reaction. The thiosemicarbazone (TSC) ligands were reacted with the ruthenium dimer [Ru(Ar)(μ-Cl)Cl](2) (Ar = benzene; p-cymene) to yield a series of
Sumit Kumar et al.
ACS omega, 3(9), 12106-12113 (2018-10-16)
1H-1,2,3-Triazole tethered imidazole-isatin and imidazole-isatin-thiosemicarbazone conjugates were synthesized and evaluated against MCF-7 and MDA-MB-231 cell lines. Antiproliferative activities of the synthesized conjugates revealed an optimum combination of longer alkyl chain length as spacer and a halogen-substituent on the isatin ring
Applications of ferrocenium salts in organic synthesis
Toma S and Sebesta R
Synthesis, 12(47), 1683-1695 (2015)
Hybrid of ferrocene and fullerene
Sawamura M, et al.
Journal of the American Chemical Society, 32(124), 9354-9355 (2002)
문서
Atomic layer deposition meets various needs including semiconductor device miniaturization and nanoparticle coating.
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