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Merck

634565

Sigma-Aldrich

Lithium perchlorate

greener alternative

battery grade, dry, 99.99% trace metals basis

동의어(들):

Lithium cloricum, Perchloric acid, lithium salt

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크기 선택

제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
LiClO4
CAS 번호:
7791-03-9
Molecular Weight:
106.39
EC Number:
232-237-2
MDL number:
MFCD00011079
UNSPSC 코드:
26111700
PubChem Substance ID:
24882632
NACRES:
NA.23
Solubility:
H2O: 106.4 g/L at 20 °C

주요 문서

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도움 문의

Quality Level

200

분석

99.99% trace metals basis

양식

powder and chunks

반응 적합성

reagent type: oxidant

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

236 °C (lit.)

solubility

H2O: 106.4 g/L at 20 °C

응용 분야

battery manufacturing

환경친화적 대안 카테고리

Enabling,

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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관련 카테고리

일반 설명

Lithium perchlorate (LiClO4) is a neutral salt with high solubility. LiClO4 finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.
Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

애플리케이션

LiClO4 can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.
LiClO4 is used as an electrolyte salt for lithium-sulfur batteries. LiClO4 acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.

픽토그램

Flame over circleCorrosionExclamation mark
GHS03,GHS05,GHS07

신호어

Danger

유해 및 위험 성명서

H272,H302,H314,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
MKCC5223
MKCB1962V
MKBZ7757V
MKBZ3598V
MKBW7838V

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문서 라이브러리 방문

Shuttle inhibitor effect of lithium perchlorate as an electrolyte salt for lithium-sulfur batteries
Kim HS, et al.
J. Appl. Electrochem., 42(2) (2012)
Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors
Sudhakar YN and Selvakumar M
Electrochimica Acta, 78, 398-405 (2012)
Solvent-free thiolysis of epoxides under lithium perchlorate catalysis.
Mojtahedi M, et al.
Monatshefte fur Chemie / Chemical Monthly, 137(4), 455-458 (2006)
Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
Yeow ML, et al.
Journal of Membrane Science , 258(1-2), 16-22 (2005)
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
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