467448
Triethylsilane
97%
동의어(들):
NSC 93579, Triethylhydrosilane, Triethylsilicon hydride
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크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
(C2H5)3SiH
CAS 번호:
Molecular Weight:
116.28
Beilstein:
1098278
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
Quality Level
분석
97%
반응 적합성
reagent type: reductant
refractive index
n20/D 1.412 (lit.)
bp
107-108 °C (lit.)
density
0.728 g/mL at 25 °C (lit.)
SMILES string
CC[SiH](CC)CC
InChI
1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
InChI key
AQRLNPVMDITEJU-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Catalyst for:
Catalyst reactivation after catalyst polymerization of styrene
Studies involving the prediction of organosilicon flash points
- Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
- Redox initiated cationic polymerization
- Beckmann rearrangement of cyclododecanone oxime
- Regioselective reductive coupling of enones and allenes
Catalyst reactivation after catalyst polymerization of styrene
Studies involving the prediction of organosilicon flash points
Triethylsilane can be used as:
- A reducing agent in the regioselective reductive coupling of enones and allenes.
- A reagent in the redox initiated cationic polymerization.
- A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
- As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
21.2 °F
Flash Point (°C)
-6 °C
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Triethylsilane- Indium (III) Chloride System as a Radical Reagent.
Hayashi N, et al.
Organic Letters, 6(26), 4981-4983 (2004)
Pd- C-induced catalytic transfer hydrogenation with triethylsilane.
Mandal PK and McMurray JS
The Journal of Organic Chemistry, 72(17), 6599-6601 (2007)
Iridium-catalyzed reduction of alkyl halides by triethylsilane.
Yang J and Brookhart M
Journal of the American Chemical Society, 129(42), 12656-12657 (2007)
Regioselective Nickel-Catalyzed Reductive Couplings of Enones and Allenes.
Li W, et al.
Angewandte Chemie (International Edition in English), 49(46), 8712-8716 (2010)
Redox-Initiated Cationic Polymerization: Reduction of Dialkylphenacylsulfonium Salts by Silanes.
Molleo M and Crivello JV
Macromolecules, 42(12), 3982-3991 (2009)
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