320129
Acetyl chloride
reagent grade, 98%
동의어(들):
Acetic acid chloride, Acetic chloride, Ethanoyl chloride
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH3COCl
CAS 번호:
Molecular Weight:
78.50
Beilstein:
605303
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
Grade
reagent grade
Quality Level
vapor density
2.7 (vs air)
vapor pressure
11.69 psi ( 20 °C)
32.33 psi ( 55 °C)
분석
98%
양식
liquid
autoignition temp.
1353 °F
expl. lim.
19 %
refractive index
n20/D 1.389 (lit.)
bp
52 °C (lit.)
mp
−112 °C (lit.)
density
1.104 g/mL at 25 °C (lit.)
작용기
acyl chloride
SMILES string
CC(Cl)=O
InChI
1S/C2H3ClO/c1-2(3)4/h1H3
InChI key
WETWJCDKMRHUPV-UHFFFAOYSA-N
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관련 카테고리
일반 설명
Acetyl chloride undergoes reaction with decalin and aluminum trichloride to afford a tricyclic enol ether. It promotes the cyclopropanation of alkene with dibromomethane or diiodomethane in the presence of Zn dust and copper chloride in ether. Friedel-Crafts reaction of acetyl chloride with benzene in the presence of MCl3 (M = Al or Fe) in the ionic liquid 1-butyl-3-methylimidazolium chloride affords MCl3 adducts of the acetyl chloride, the acetylium ion [CH3CO]+[MCl4]- and the MCl3 adduct of acetophenone.
애플리케이션
- Synthesis, Characterization, and Evaluation of Thiazolidine Derivatives of Cysteine for Suppressing Eumelanin Production.: The study discusses the synthesis and evaluation of thiazolidine derivatives of cysteine, where acetyl chloride is used as a reagent, underscoring its importance in pharmaceutical intermediate development. (Amino et al., 2016).
- New URJC-1 Material with Remarkable Stability and Acid-Base Catalytic Properties.: This research introduces the new URJC-1 material, noting its stability and catalytic properties, with acetyl chloride being pivotal in the synthesis process, illustrating its role in material science and catalysis. (Leo et al., 2016).
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
41.0 °F - closed cup
Flash Point (°C)
5 °C - closed cup
In situ infrared spectroscopic studies of the Friedel-Crafts acetylation of benzene in ionic liquids using AlCl3 and FeCl3.
Csihony S, et al.
Green Chemistry, 3(6), 307-309 (2001)
Acetyl chloride promoted cyclopropanations of alkenes with dibromomethane using zinc dust and copper (I) chloride in ether.
Friedrich EC and Lewis EJ.
The Journal of Organic Chemistry, 55(8), 2491-2494 (1990)
Catherine L Lyall et al.
Journal of the American Chemical Society, 136(39), 13745-13753 (2014-09-10)
Decalin undergoes reaction with aluminum trichloride and acetyl chloride to form a tricyclic enol ether in good yield, as first reported by Baddeley. This eye-catching transformation, which may be considered to be an aliphatic Friedel-Crafts reaction, has not previously been
Facile catalyzed acylation of alcohols, phenols, amines and thiols based on ZrOCl 2? 8H 2 O and acetyl chloride in solution and in solvent-free conditions.
Ghosh R, et al.
Tetrahedron Letters, 46(1), 147-151 (2005)
Oxetanes. VII. Synthesis from 1, 3-Diols. Reactions of Oxetanes and of 1, 3-Butanediol with Hydrogen Chloride, Hydrogen Bromide and Acetyl Chloride1, 2.
Searles JS, et al.
Journal of the American Chemical Society, 79(4), 952-956 (1957)
문서
Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.
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