262099
Phosphorus(V) oxychloride
99.999%
동의어(들):
Phosphorus(V) oxide chloride, Phosphoryl chloride
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
POCl3
CAS 번호:
Molecular Weight:
153.33
EC Number:
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22
Bp:
105.8 °C (lit.)
Vapor pressure:
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
28 mmHg ( 20 °C)
vapor density
5.3 (vs air)
Quality Level
vapor pressure
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
분석
99.999%
양식
liquid
pH
1 (20 °C)
bp
105.8 °C (lit.)
mp
1.25 °C (lit.)
density
1.645 g/mL at 25 °C (lit.)
작용기
phosphine oxide
SMILES string
ClP(Cl)(Cl)=O
InChI
1S/Cl3OP/c1-5(2,3)4
InChI key
XHXFXVLFKHQFAL-UHFFFAOYSA-N
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애플리케이션
Phosphorus(V) oxychloride can be used as:
It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.
- A dehydrating agent in organic synthesis.
- A reagent in the cyclization of substituted aryl amides by Bischler−Napieralski cyclization reaction.
- A precursor for phosphorus diffusion in the p-type silicon solar cells processing.
It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation
표적 기관
Respiratory Tract
보충제 위험성
Storage Class Code
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Isocyanide 2.0
Patil P, et al.
Green Chemistry, 22(20), 6902-6911 (2020)
Optimization of phosphorus emitter formation from POCl 3 diffusion for p-type silicon solar cells processing
Ghembaza H, et al.
Silicon, 10(2), 377-386 (2018)
Patrick J O'Brien et al.
Biochemistry, 41(9), 3207-3225 (2002-02-28)
Escherichia coli alkaline phosphatase (AP) is the prototypical two metal ion catalyst with two divalent zinc ions bound approximately 4 A apart in the active site. Studies spanning half a century have elucidated many structural and mechanistic features of this
Gül Altınbaş Ozpınar et al.
Journal of molecular modeling, 17(12), 3209-3217 (2011-03-03)
Because of discrepancies in the available experimental data, an extensive theoretical investigation of the formation of the Vilsmeier-Haack (VH) complex has been carried out. The barriers to complex formation calculated using eight different density functional methods (BLYP, B2-PLYP, B3LYP, B3PW91
Eric S Melby et al.
PloS one, 6(4), e18420-e18420 (2011-04-13)
Phosphorus (P) has only one stable isotope and therefore tracking P dynamics in ecosystems and inferring sources of P loading to water bodies have been difficult. Researchers have recently employed the natural abundance of the ratio of (18)O/(16)O of phosphate
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