201170
Phosphorus(V) oxychloride
ReagentPlus®, 99%
동의어(들):
Phosphorus(V) oxide chloride, Phosphoryl chloride
로그인조직 및 계약 가격 보기
크기 선택
제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
POCl3
CAS 번호:
Molecular Weight:
153.33
EC Number:
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22
Bp:
105.8 °C (lit.)
Vapor pressure:
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
28 mmHg ( 20 °C)
vapor density
5.3 (vs air)
Quality Level
vapor pressure
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
제품 라인
ReagentPlus®
분석
99%
양식
liquid
dilution
(for general lab use)
pH
1 (20 °C)
bp
105.8 °C (lit.)
mp
1.25 °C (lit.)
density
1.645 g/mL at 25 °C (lit.)
작용기
phosphine oxide
SMILES string
ClP(Cl)(Cl)=O
InChI
1S/Cl3OP/c1-5(2,3)4
InChI key
XHXFXVLFKHQFAL-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Phosphorus(V) oxychloride (POCl3) is a chlorinating agent that reacts with dimethylformamide (DMF) to form Vilsmeier reagent for Vilsmeier-Haack formylation reactions.
It can also be used as a reagent in the synthesis of:
It can also be used as a reagent in the synthesis of:
- Quinazolin-4(3H)-one derivatives from 2-aminobenzamides via in situ preparation of Vilsmeier reagent.
- Substituted 1-arylseleno-4-halo-2-enes by treating conjugated dienes with arylselenenamides.
- 3-methylthioimidazo[1,2-a]pyridines and imidazo-fused heterocycles in the presence of DMSO.
포장
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation
표적 기관
Respiratory Tract
보충제 위험성
Storage Class Code
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
DMSO-POCl3: a reagent for methylthiolation of imidazo [1, 2-a] pyridines and other imidazo-fused heterocycles
Patil SM, et al.
Tetrahedron, 69(38), 8255-8262 (2013)
Arylselenenation of conjugated dienes by arylselenenamides in the presence of phosphorus (V) oxyhalides
Antipin RL, et al.
Tetrahedron Letters, 48(4), 729-731 (2007)
Vilsmeier-Haack formylation of 2-(1H-pyrazol-1-yl) ethanol and its methyl derivatives.
Rstakyan VI, et al.
Russ. J. Gen. Chem., 85(5), 1191-1193 (2015)
Vilsmeier Reagent: An Efficient Reagent for the Transformation of 2-Aminobenzamides into Quinazolin-4 (3 H)-one Derivatives.
Farzipour S, et al.
Synthetic Communications, 44(4), 481-487 (2014)
Patrick J O'Brien et al.
Biochemistry, 41(9), 3207-3225 (2002-02-28)
Escherichia coli alkaline phosphatase (AP) is the prototypical two metal ion catalyst with two divalent zinc ions bound approximately 4 A apart in the active site. Studies spanning half a century have elucidated many structural and mechanistic features of this
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