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703486

sec-Butylmagnesium chloride lithium chloride complex solution

1.2 M in THF

Synonym(s):

2-Butylmagnesium chloride lithium chloride complex, Turbo Grignard

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About This Item

Linear Formula:
C4H9MgCl · LiCl
Molecular Weight:
159.27
UNSPSC Code:
12352001
PubChem Substance ID:
329762042
NACRES:
NA.22
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form

liquid

reaction suitability

reaction type: Grignard Reaction

concentration

1.2 M in THF, 14 % (w/w)

density

0.973 g/mL at 25 °C

SMILES string

[Li]Cl.CCC(C)[Mg]Cl

InChI

1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q;;;2*+1/p-2

InChI key

ZMDHAYOBNXOYEU-UHFFFAOYSA-L

Application

Reagent for Selective Metalations

Used as:
  • Functionalization of cyclopentene derivatives

Legal Information

Product of Albemarle US Inc

signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

-6.7 °F

flash_point_c

-21.5 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

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Articles

Selective Metalations

Salt additives increase both the rate and the efficiency of the Mg-halogen exchange reaction. The most effective reagents are generated with R-MgCl (R = i-Pr, s-Butyl) and 1.0 equiv of LiCl.

Global Trade Item Number

SKUGTIN
703486-800ML04061837674891
703486-100ML04061837674884