328219
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
solid
Synonym(s):
1,2-Ethylenebis(diphenylphosphine)nickel dichloride, Nickel 1,2-Bis(diphenylphosphino)ethane dichloride, [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride, dppeNiCl2
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About This Item
Product Name
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II),
form
solid
Quality Level
reaction suitability
core: nickel, reagent type: catalyst
mp
263-265 °C (lit.)
SMILES string
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI
1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI key
XXECWTBMGGXMKP-UHFFFAOYSA-L
Application
- Kumada catalyst-transfer polycondensation
- Oxidation of carboranyl phosphine ligands
- Synthesis of nickel-iron dithiolato hydrides
- Ullmann reactions - homocoupling reactions
Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers
Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
14647-23-5
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 328219-25G | 04061833546611 |
| 328219-1G | 04061826662335 |
| 328219-5G | 04061833321645 |