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34857

1,4-Dioxane

suitable for HPLC, ≥99.5%

Synonyme(s) :

Dioxane, Oxyde de diéthylène

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A propos de cet article

Formule empirique (notation de Hill) :
C4H8O2
Numéro CAS:
Poids moléculaire :
88.11
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-661-8
Beilstein/REAXYS Number:
102551
MDL number:
Assay:
≥99.5%
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Bp:
100-102 °C (lit.)
Vapor pressure:
27 mmHg ( 20 °C), 40 mmHg ( 25 °C)
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grade

HPLC grade

Quality Level

vapor density

3 (vs air)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

≥99.5%

form

liquid

autoignition temp.

356 °F

expl. lim.

22 %

technique(s)

HPLC: suitable

impurities

≤0.001% non-volatile matter, ≤0.002% free acid (as CH3COOH), ≤0.01% peroxides (as H2O2), ≤0.05% water (Karl Fischer)

transmittance

220 nm, ≥20%, 270 nm, ≥80%, 300 nm, ≥98%

refractive index

n20/D 1.422 (lit.)

pH

6.0-8 (20 °C, 500 g/L)

bp

100-102 °C (lit.)

mp

10-12 °C (lit.)

density

1.034 g/mL at 25 °C (lit.)

UV absorption

λ: 220 nm Amax: ≤0.70, λ: 235 nm Amax: ≤0.50, λ: 250 nm Amax: ≤0.20, λ: 270 nm Amax: ≤0.10, λ: 295-400 nm Amax: ≤0.01

application(s)

food and beverages

SMILES string

C1COCCO1

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

InChI key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

General description

1,4-Dioxane is widely used as a solvent for various organic compounds in industry. It is a non-biodegradable contaminant found in industrial effluents. Its oxidative degradation by using oxygen and ozone has been useful in converting it into biodegradable products, which can be easily removed by conventional methods.

Application

Convient à la HPLC, à la spectrophotométrie, et aux tests environnementaux
High-purity, multipurpose solvent, tested for suitability in:
  • HPLC
  • Spectrophotometry
  • Residual testing
  • LC-MS applications.

Reported as a solvent in:
  • HPLC-MS study of fat-soluble vitamins (FSVs)
  • GC-MS analysis of phthalates in workplace air

1,4-Dioxane may be employed as a solvent in the synthesis of N-(4-(prop-2-ynyloxy)phenyl)acetamide and 3-(4-(prop-2-ynyloxy)phenyl)-3,4-dihydro-2H-benzo[e][1,3]oxazine.

Other Notes

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signalword

Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Classe de stockage

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup



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Consulter la Bibliothèque de documents



Oxidation and biodegradability enhancement of 1,4-dioxane using hydrogen peroxide and ozone.
C D Adams et al.
Environmental science & technology, 28(11), 1812-1818 (1994-10-01)
Self-curable benzoxazine functional polybutadienes synthesized by click chemistry.
Kukut M, et al.
Designed Monomers and Polymers, 12(2), 167-176 (2009)
Xiaohua Liu et al.
Biomaterials, 31(2), 259-269 (2009-09-29)
It remains a challenge to synthesize functional materials that can develop advanced scaffolding architectures for tissue engineering. In this study, a series of biodegradable amphiphilic poly(hydroxyalkyl (meth)acrylate)-graft-poly(l-lactic acid) (PHAA-g-PLLA) copolymers have been synthesized and fabricated into nano-fibrous scaffolds. These copolymers



Numéro d'article de commerce international

RéférenceGTIN
34857-1L04061838443083
34857-6X1L04061826763605
34857-100ML04061826763490
34857-2.5L04061841258841
34857-2L04061838443090
34857-500ML04061838443106
34857JP-4X2.5L04061837289408
34857JP-6X1L04061837289415