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MilliporeSigma

30315

Iodure de potassium

puriss. p.a., reag. ISO, reag. Ph. Eur., ≥99.0%

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A propos de cet article

Formule linéaire :
KI
Numéro CAS:
Poids moléculaire :
166.00
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-659-4
MDL number:
Assay:
≥99.0%, 99.0-100.5% (calc. to the dried substance)
Form:
solid
Solubility:
water: complete (ca.1,430 g/l at 25 °C (77 °F))
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Quality Level

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor pressure

1 mmHg ( 745 °C)

description

REDUCING SUBSTANCES complying

grade

puriss. p.a.

assay

≥99.0%, 99.0-100.5% (calc. to the dried substance)

form

solid

impurities

≤0.0005% heavy metals (as Pb), ≤0.001% total nitrogen (N), ≤0.005% thiosulfate (S2O3), ≤0.02% free alkali (as KOH)

loss

≤0.5% loss on drying, 105 °C

pH

6.0-8.0 (20 °C, 5%)

mp

681 °C (lit.)

solubility

water: complete (ca.1,430 g/l at 25 °C (77 °F))

anion traces

bromide, chloride (as Cl-): ≤100 mg/kg, iodate (IO3-): ≤2 mg/kg, phosphate (PO43-): ≤10 mg/kg, sulfate (SO42-): ≤10 mg/kg

cation traces

As: ≤0.1 mg/kg, Ba: ≤20 mg/kg, Ca: ≤10 mg/kg, Fe: ≤3 mg/kg, Mg: ≤10 mg/kg, Na: ≤300 mg/kg

SMILES string

[K+].[I-]

InChI

1S/HI.K/h1H;/q;+1/p-1

InChI key

NLKNQRATVPKPDG-UHFFFAOYSA-M

General description

Potassium iodide (KI) is a chemical compound that can be used as an iodide ion source for nucleophilic displacement reactions. During the electrochemical oxidation of aldehydes, it acts as a mediator. In the presence of an acid, it can cleave some ethers. KI can iodinate aromatic and organothallium compounds in the presence of an oxidizing agent. Additionally, it can form symmetrical thiosulfonic S-esters by reacting with sulfonyl chlorides.

Application

Potassium iodide is used as:
  • An iodine source in the synthesis of 1-iodoalkynes and iodophenols from alkynes and phenols using tert-butyl hydroperoxide (TBHP) as oxidant.
  • A catalyst in the synthesis of sulfonated oxindoles by arylsulfonylation of activated alkenes using sulfonylhydrazides as sulfonyl precursor, and water as solvent.
  • An oxidative degradation inhibitor to reduces oxidative degradation of monoethanolamine (MEA).



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signalword

Danger

target_organs

Thyroid

Classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

pictograms

Health hazardExclamation mark

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - STOT RE 2



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Y Miyachi et al.
The British journal of dermatology, 107(2), 209-214 (1982-08-01)
The effects of potassium iodide, colchicine and dapsone on the in vitro generation of polymorphonuclear leukocyte (PMN)-derived oxygen intermediates were investigated. These three drugs have beneficial effects on those conditions in which PMNs play an important pathogenetic role. Three oxygen
H B Li et al.
Journal of chromatography. A, 918(2), 335-339 (2001-06-16)
A novel method for the determination of iodide by size exclusion chromatography was established. The method was simple and highly sensitive with good precision. Iodide was converted to iodine, then sequestered with starch, and separated from the matrix using a
V Witko-Sarsat et al.
Journal of immunology (Baltimore, Md. : 1950), 161(5), 2524-2532 (1998-09-02)
We previously demonstrated the presence of advanced oxidation protein products (AOPP), a novel marker of oxidative stress in the plasma of uremic patients receiving maintenance dialysis. The present study in a cohort of 162 uremic patients showed that plasma concentrations



Numéro d'article de commerce international

RéférenceGTIN
30315-100G04061835562022
30315-250G04061826666258
30315-6X1KG04061835562060
30315-6X250G04061832993492
30315-1KG04061835562039
30315-500G04061835562053