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MilliporeSigma

180173

Sulfure de carbone

ACS reagent, ≥99.9%

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A propos de cet article

Formule empirique (notation de Hill) :
CS2
Numéro CAS:
Poids moléculaire :
76.14
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-843-6
Beilstein/REAXYS Number:
1098293
MDL number:
Assay:
≥99.9%
Grade:
ACS reagent
Bp:
46 °C (lit.)
Vapor pressure:
5.83 psi
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grade

ACS reagent

Quality Level

vapor density

2.67 (vs air)

vapor pressure

5.83 psi

assay

≥99.9%

form

liquid

autoignition temp.

212 °F

expl. lim.

50 %

dilution

(for analytical testing)

impurities

H2S, passes test (lim. ~1.5 ppm), SO2, passes test (lim ~2.5 ppm), ≤0.05% water

evapn. residue

≤0.002%

color

APHA: ≤10

refractive index

n20/D 1.627 (lit.)

bp

46 °C (lit.)

mp

−112-−111 °C (lit.)

density

1.266 g/mL at 25 °C (lit.)

SMILES string

S=C=S

InChI

1S/CS2/c2-1-3

InChI key

QGJOPFRUJISHPQ-UHFFFAOYSA-N

General description

Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.
Carbon disulfide (CS2) is a colorless liquid. It is present in atmosphere and natural waters in the form of sulfur gas. It is responsible for the production of sulfur dioxide (SO2) in the atmosphere (stratosphere and/or troposphere). Its lifetime in the atmosphere has been proposed to be around 12 days. It is a non-polar solvent.
Carbon disulfide is a highly volatile, flammable liquid with low ignition temperature. It can be synthesized by reacting hydrocarbon gas with sulfur. It is an important raw material for preparing viscose rayon and cellophane film.

Application

Carbon disulfide has been used for the desorption of air samples during analysis of trihalomethanes (THMs) in those samples.
It may be used in the preparation of dibenzyl trithiocarbonate, a RAFT (Reversible Addition-Fragmentation Transfer) chain-transfer agent (CTA). It may be employed as a solvent in the preparation of benzyl chlorodithioformate.
Carbon disulfide may be used in the xanthogenation of cellulose and in the synthesis of poly(ethylene trithiocarbonate) and dithiocarbamates. C2S may undergo hydrolysis catalyzed by nanosized titania and zirconia to form CO2 and H2S. It can also generate 1,3-dithiolium carbenes via cycloaddition with acetylenes.


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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1

target_organs

Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes

Classe de stockage

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-22.0 °F - closed cup

flash_point_c

-30 °C - closed cup



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Copolymerization of ethylene sulfide and carbon disulfide.
Soga K, et al.
Journal of Polymer Science, 14(3), 677-684 (1976)
Carbon Disulfide.
Smith DE and Timmerman RW.
Kirk-Othmer Encyclopedia of Chemical Technology (2003)
An efficient, one-pot, synthesis of dithiocarbamates from the corresponding alcohols using Mitsunobu's reagent.
Chaturvedi D and Ray S.
Tetrahedron Letters, 47(8), 1307-1309 (2006)



Numéro d'article de commerce international

RéférenceGTIN
180173-4L-AB04065274090801
180173-500ML04061838754721
180173-1L-AB04065274090795
180173-1L04061838260529
180173-2L04061838754714